Page 144 - Handbook of Adhesion Promoters

7.31 Titanates 137

7.31 TITANATES

GENERAL INFORMATION
Name: Tyzor CAS #: 17927-72-9, 68568-02-7, 546-68-9, 445398-76-5,
109037-78-7
Active matter, wt%: 60-100
Composition: 16.40% (TiO ), bis(acetylacetonate) diisopropoxide titanium, 13-30% propan-2-ol,
2
3-7% methanol, 3-7% butan-1-ol; 15% (TiO ), titanium acetylacetonate, 25% isopropyl alcohol,
2
10% ethanol; 28.1% (TiO ), tetra-iso-propyl titanate
2
Empirical formula: C16H28O6Ti; C15H26O8Ti Molecular mass: 364-382
PHYSICAL PROPERTIES
3
o
o
Boiling point, C: 70-232 Density, at 20 C, kg/m : 950-1120
Color: colorless, yellow, red Solubility (diluents): most organic solvents
o
o
Viscosity at 25 C, mPa s: 3.5-90 Melting point, C: 19
o
o
Solubility in water at 25 C, g/l: moisture sensitive Pour point, C: -70 to -25
State: liquid Refractive index, n 20 : 1.477
D
HEALTH AND SAFETY
o
Autoignition temp., C: 386 HMIS: fire, health, reactivity: 3, 2, 0
o
Flash point, C: 12-90 NFPA: fire, health, reactivity: 3, 2, 0
DOT, shipping name: Flammable liquids, n.o.s.(Propan-2-ol, Methanol)
LD50, oral rat, mg/kg: 5045/propan-2-ol, 5628/methanol, 790/butan-1-ol
LD50, dermal rabbit, mg/kg: 12800/propan-2-ol, 15800/methanol, 3400/butan-1-ol
3
LC50 inhalation, rat, mg/m : 30000/propan-2-ol
Hazardous combustion products: carbon monoxide, carbon dioxide, metal oxides
Labelling (hazardous ingredients): Flammable liquids, n.o.s.(Titanium, Bu phosphate Et alc. iso-
Pr alc. Complexes), special provision 640D, Environmentally hazardous
3
ACGIH, mg/m : 984/ST/propan-2-ol, 328/ST/methanol UN/NA class: 1993
3
OSHA PEL, mg/m : 1225/ST/propan-2-ol, 325/ST/methanol, 300/LT/butan-1-ol
ACGIH, ppm: 400/ST/propan-2-ol, 250/ST/methanol
OSHA, ppm: 400/ST/propan-2-ol, 250/ST/methanol, 100/LT/butan-1-ol
ENVIRONMENTAL IMPACT
EC50, Daphnia magna, 48h, mg/l: 10000
USE
Manufacturer: Dorf Ketal Chemicals, LLC