Page 142 - Handbook of Adhesion Promoters

7.29 Sucrose derivatives 135

DOT, shipping name: Flammable liquids, n.o.s. (ethanol, methanol) 3, ll. Shipping descriptions
may vary based on mode of transport, quantities, package size, and/or origin and destination to not
regulated
ICAO/IATA class: Flammable liquid, n.o.s. (ethanol, methanol) 3, ll. Shipping descriptions may
vary based on mode of transport, quantities, package size, and/or origin and destination to not reg-
ulated
LD50, oral rat, mg/kg: 25600/sucrose acetate isobutyrate, 10470/ethanol, 5628/methanol, 2000/
methyl isobutyl ketone
LD50, dermal rabbit, mg/kg: >15800/ethanol, 17100/methanol, >10/methyl isobutyl ketone,
20000/ethyl acetate
3
LC50 inhalation, rat, mg/m : 64000ppm/4H/methanol, <4000ppm/isobutyl methyl ketone,
6000ppm/6H/ethyl acetate
Hazardous combustion products: carbon monoxide and carbon dioxide
3
NIOSH REL, mg/m : ST325/methanol
ACGIH, ppm: 200/methanol,1000/ethanol, 20/isobutyl methyl ketone, 400/ethyl acetate
3
OSHA PEL, mg/m : 260/methanol; 1900/ethanol, 410/isobutyl methyl ketone, 1400/ethyl acetate
OSHA, ppm: 1000/ethanol, 100/isobutyl methyl ketone, 400/ UN/NA class: 1993, 1173
ethyl acetate
ENVIRONMENTAL IMPACT
EC50, green algae, 96h, mg/l: 275/72H/ethanol
EC50, Bluegill sunfish, 96h, mg/l: 15400/methanol
EC50, Daphnia magna, 96h, mg/l: 4300/24H/isobutyl methyl ketone
EC50, Daphnia magna, 48h, mg/l: >1.11/sucrose acetate isobutyrate, >10000/methanol
EC50, Fathead minnow, 96h, mg/l: >1.82/sucrose acetate isobutyrate, 15300/ethanol
BOD20, g/g: 1.260/methanol, 1.240-1.430/ethyl acetate
BOD5, g/g: 0.770/methanol, 1.94-2.06/isobutyl methyl ketone, 1.240/ethyl acetate
Chemical oxygen demand COD, g/g: 1.63/sucrose acetate isobutyrate, 1.99/ethanol, 1.44/metha-
nol, 2.16-2.46/isobutyl methyl ketone
Partition coefficient, log K : 6.00/sucrose acetate isobutyrate
ow
USE
Manufacturer: Eastman Chemical Company
Outstanding properties: Derived from a natural, renewable source (sucrose, a natural sugar).
Improved adhesion to fingernails, chip and scratch resistance, leveling of brush strokes, increased
film flexibility. Decreased evaporation rate of fragrance ingredients. Excellent solubility and com-
patibility with solvents, polymers, and modifiers. Low volatility over a wide temperature range.
Nonyellowing; stable to UV light exposure. Increased water resistance of films. Enhanced gloss.
Compatible with large number of resins, plasticizers, oils, humectants used in cosmetics.
Recommended for products: cosmetics: nail lacquers, lipstick, lip gloss, mascara, foundation,
concealer; lacquers, coatings, textiles
Food approval (FDA): lacquers, coatings, textiles