Page 190 - Handbook of Adhesion Promoters
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9.6 Ceramic tiles                                                    183


































            Figure 9.1. PVAl mortar/vinyl active surface interaction model. [Adapted, by permission, from Mansur, AAP;
            Mansur, HS, Cement Concrete Compos., 33, 742-8, 2011.]
            9.6 CERAMIC TILES
            The ANSI standards 118-15 and 118-11 facilitate the design of high-performance ceramic
                                                                               1
            tile adhesives with improved bond strength on cementitious and plywood substrates.  The
            investigation of properties of mortars shows that the rheology (proportion of water and
                                                   1
            cement) has the strongest influence on adhesion.
                Adhesion mechanisms and interfacial strengths of polyvinylalcohol-modified mortar
                                                                   2
            and chemically active tiles with five different silanes were studied.  Hydrophilic silane
            functionalities  and  isocyanate  groups  improved  interfacial  strength  between  tiles  and
                         2
            modified mortar.  The silanes bearing hydrophobic functional group decreased adhesion
                               2
            resistance (Figure 9.1).  The hydrophilic silanes formed bonds with PVAl cement modi-
               2
            fier.
            REFERENCES
            1  Petit, J-Y; Comelli, B; Perrin, R; Wirquin, E, Int. J. Adh. Adh., 66, 73-80, 2016.
            2  Mansur, AAP; Mansur, HS, Cement Concrete Compos., 33, 742-8, 2011.
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