Page 81 - Handbook of Adhesion Promoters
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74                                     Substrates - Surface Condition and Treat-

























            Figure 4.23. Schematic illustration of the synthesis and deposition of ZnO nanocrystals on the surface in the
            presence of ultrasonic irradiation. The asymmetric collapse near the surface by the generation of microjets as
            strong streams results in the particles joining and the formation of the flower-like structure. [Adapted, by permis-
            sion, from Sharifalhoseini, Z; Entezari, MH; Jalal, R, Surf. Coat. Technol., 266, 160-6, 2015.]

                                                     The adhesion and proliferation of bac-
                                                 teria on metallic surfaces in health centers,
                                                 industries,  and homes  increase the risk of
                                                                59
                                                 human  infections.   A  mild  steel  was
                                                 coated with a Ni-P layer through electroless
                                                                               59
                                                 plating  to  prevent  surface  corrosion.  To
                                                 achieve  an  antibacterial  metallic  surface,
                                                 simultaneous  sono-synthesis  and  deposi-
                                                 tion of ZnO nanoparticles were performed
                                                                             59
                                                 on the Ni-P coating (Figure 4.23).  Figure
                                                 4.24b shows  the presence of peaks attrib-
                                                                    59
                                                 uted  to  the Ni-P  phase.   The  micrograph
                                                 4.24c shows in addition ZnO nanoparticles
                                                 which  form  characteristic  needle-like
                                                                           59
                                                 shapes, attached to Ni-P surface.  Escheri-
                                                 chia coli  showed  some  biological  activity
                                                 on Ni-P layer but the plate containing ZnO
                                                 nanoparticles  effectively  prohibited  the
                                                               59
                                                 growth of E. coli.  This suggests that ZnO
                                                 surface  could  be  utilized  for  antibacterial
                                                                                 59
                                                 purposes and reduction of colonization.

            Figure 4.24. 3D scanning micrographs. (b) Ni-P coat-
            ing, (c) zinc oxide nanoparticles. [Adapted, by permis-
            sion, from Sharifalhoseini, Z; Entezari, MH; Jalal, R,
            Surf. Coat. Technol., 266, 160-6, 2015.]
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