Page 608 - Handbook of Battery Materials

582 17 Liquid Nonaqueous Electrolytes

Table 17.15 (continued)

Solid Liquid Method Species References
phase/ phase/
electrode electrolyte

Li LiOTf – THF FTIR, Li 2 O, CF 3 bonds [354]
ESCA
Li LiPF 6 – DEC FTIR, XPS LiF, Li 2 O [355]
Li LiPF 6 –DMC, DMFTRI, LiO 2 COR (from EC [342, 387]
EC AFM and DMC), CO 2
Li LiPF 6 – PC XPS Mainly LiF [342]
Li/TiS 2 LiAsF 6 – XPS LiAs(OR) x F 6-x , [388]
2-Me-THF (As-O) n ,As 0
Li/TiS 2 LiAsF 6 – EDS, As, F,C,O,S, [389]
2-Me-THF ESCA, (elements), OH,
FTIR CH, CF, AsF
(groups), LiOR,
AsF 3 ,As 2 O 3 ,LiF,
0
As , (As-O) n
Li/TiS 2 LiAsF 6 – XPS, FTIR LiF, Li 2 O, LiO 2 SR, [390]
2-Me-THF LiSR ,SR,SR ,

OSR, (As-S) n ,
R = (CH 2 ) 2 −

CH(CH 3 –CH 2 ,R =
CH 2 =
C(CH 3 ) − (CH 2 ) 2
Graphite b(i) LiAsF 6 –DEC, FTIR Li 2 CO 3 (traces), [62, 63]
EC (LiO 2 COCH 2 ) 2
(from EC)
Graphite b(i) LiAsF 6 − DEC, FTIR Li 2 CO 3 ,few [62, 63]
EC, (LiO 2 COCH 2 ) 2
p(CO 2 ) = 6 atm (from EC)
Graphite LiAsF 6 –DMC, FTIR, Main product [334]
EC XPS, (LiO 2 COCH 2 ) 2
XRD,
SEM
Graphite b(ii) LiAsF 6 – MPC FTIR LiO 2 COR, Li 2 CO 3 [335]
Graphite b(iii) LiAsF 6 –SO 2 , FTIR LiO 2 COR, Li 2 CO 3 , [364]
PC Li x AsF y ,Li 2 S 2 O 4 ,
Li 2 S, Li 2 SO 3 ,
Li 2 S 2 O 5 ,
LiO 2 COCH 2 O(OCO 2 Li)
CHCH 3
Graphite b(i) LiBF 4 –DEC, FTIR Small carbonate [62, 63]
EC content, B–F bonds