Page 607 - Handbook of Battery Materials

17.4 Bulk Properties 581

Table 17.15 (continued)

Solid Liquid Method Species References
phase/ phase/
electrode electrolyte

Li LiClO 4 –DIOX FTIR LiOR, LiOH [380]
(H 2 O)
Li LiClO 4 –DME, FTIR (in LiOR (DME), [376]
PC situ) LiO 2 COR (PC)
Li LiClO 4 – PC XPS, Li 2 CO 3 , LiCl, [342, 350, 381–383]
FTIR, IR, LiClO 4 ,Li 2 O, LiOH
DMFTIR,
AES
Li LiClO 4 – PC XRD LiCl, LiClO 4 , [384–386]
Li 2 CO 3 (in
polymers on top),
Li 2 Odense on
bottom
Li LiClO 4 –PC FTIR (in LiO 2 COR, Li 2 CO 3 [369]
(H 2 O) situ) (from water)
Li LiMe – DIOX FTIR Li 2 CO 3 ,LiO 2 COR, [337]
LiOR, LiO 2 CH,
S–O, C–S, C–F
(from anion)
Li LiTFSI – DIOX FTIR LiOR, LiO 2 CH, [337]
N–S, S 2 O–N, S 2 O,
S–O, C–S, C–F,
CF 3 bonds (from
anion)
Li LiTFSI – PC FTIR, Mainly Li 2 O, Li 3 N, [354]
ESCA Li 2 CO 3 ,few
LiO 2 COR, C–F,
C–S, C–O, SO 2 ,
CF 3 ,SO 2 –N bonds
Li LiTFSI – PC, FTIR, Li 2 CO 3 (main [354]
CO 2 ESCA compound)
Li LiTFSI – THF FTIR, Li 2 O, SO 2 –N, CF 3 [354]
ESCA bonds
Li LiOTf – PC FTIR, Mainly Li 2 O, LiF, [350, 354]
ESCA, few LiO 2 COR,
XPS, IR Li 2 CO 3 , C–F, C–S,
C–O, SO 2 ,CF 3
bonds
Li LiOTf – PC, CO 2 FTIR, Li 2 CO 3 (main [354]
ESCA compound)
(continued overleaf)