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Tensile failure of polyester fibers                                481

              Stress-strain curves can be parameterized by characteristic points determined by
           smoothing and differentiation (Schultze-Gebhardt, 1979; Sujica and Smole, 2003;
           Militký and Vaní  cek, 1991). It is not necessary to find the approximation function
           s(ε), in a closed form, but smoothed (noiseless) data for graphical interpretation,
           numerical differentiation, and integration are required. The purpose of numerical
           smoothing is to remove the random noise ε i in experimental data and the reconstruc-
           tion of noiseless function s(ε). A smoothing function s(ε) must be continuous in the
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           first two derivatives only. Therefore a nonparametric C spline smoothing of the exper-
           imental stress-strain curve, determined by the couples s i ; ε i  i ¼ 1.N, is useful
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           (Meloun et al., 1994). It has been shown that the function s(ε) from class C , which
           minimizes a combination of the smoothness of s(ε) and its closeness to the experi-
           mental points, has the following properties:
           •  The function s(ε) in each interval I j ˛ðε iþ1 ; ε i Þ is a polynomial of at most third degree.
           •  At all locations ε i , the function s(ε) is a continuous function and in the values of the first two
              derivatives.
              The full procedure of spline smoothing is described in Meloun et al. (1994). From
           the smoothed function s(ε) the shape of the first (modulus E ¼ ds/dε) and second (rate
                            2
                        2
           modulus D ¼ d s/dε ) derivatives can be simply determined.
              Fig. 13.28 shows a typical smoothed stress-strain curve together with the curves of
           the modulus E and rate modulus D.
              From the extremes on the curves for E and D it is possible to exactly define five
           characteristic points on the stress-strain curve:
           1. The point of the first maximum on the modulus curve (E). The corresponding modulus E 0 is
              used as the initial modulus characterizing the initial resistance to the deformation.
           2. The point of the first minimum on the rate modulus curve (D). It corresponds to the yield
              point characterizing the start of marked plastic deformation. It is therefore related to the
              elastic recovery of the fibers.



                     (a)               (b)
                                  5      σ
                               4
                      σ
                         2 3
                        1                σ f                      f
                          ε
                      E

                          ε                E 0
                      D


                          ε               0          ε            ε f
           Figure 13.28 Characteristic points on the stress-strain curve (schematically). (a) Smooth curve
           and its first two derivatives. (b) Basic characteristic.
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