Page 58 - Handbook of Surface Improvement and Modification
P. 58

4






                      Surface Matting (Flattening)




            4.1 METHODS AND MECHANISMS OF FLATTENING

                                          The mechanism of flattening is similar to the mecha-
                                          nism of glossiness. The surface finish of a material
                                          depends on how the smooth or rough surface is. The
                                          roughness of surface correlates with light reflection
                                          and gives the perception of surface condition. Cus-
                                          tomers of products discussed in the previous chapter
                                          had a preference for a glossy finish but many prod-
                                          ucts required  a  matte  finish, such as  coatings, coil
                                          coatings, cosmetics, flooring, leather, paints, powder
                                          coatings, printing inks, and wood.
                                              A  typical  method  of  varying  surface  gloss
                                          includes  a  variation  of  proportion  between  binder
                                          and filler. The more binder the higher the gloss of
                                          the material. Materials are usually divided into flat
                                          (less than 10% reflection), low sheen, eggshell, semi
                                          glossy, and glossy (more than 70% reflection). The
                                          glossy material has usually purely organic composi-
                                          tion. The flat material has substantial part of the sur-
                                          face made out of flattening additive. The flattening
                                          additives can be either organic or inorganic. In the
                                          case of organic additives, a very fine, uniform sur-
                                          face texture can be produced in a reproducible man-
                                          ner.  Such  surface  also  provides  a  soft-feel  effect.
                                          Figure 4.1 shows that, depending on the composition
                                          and  the  amount  of  fillers,  a  material  can  be  made
            Figure 4.1. SEM image of different glazes.   transparent,  opaque,  and  opaque  and  matte.  It  is
            1: zirconia-based opaque glaze, 2: calcium   more  challenging  to  obtain  both  transparent  and
            and zinc-based matte glaze, 3: titania-based
            opaque glaze, and 4 transparent glaze.  matte  material.  The  use  of  inorganic  additives
            [Adapted, by permission, from Sheikhattar,   improves in addition abrasion, anti-scratch, and mar
            M; Attar, H; Sharafi, S; Carty, WM, Mater.   resistance. In the next section, six types of matting
            Charact., 118, 570-4, 2016.
                                          additives  (wax,  polymeric  wax,  polycondensate,
            polyurethane beads, silicon dioxide, and wax-modified silicon dioxide) are discussed.
   53   54   55   56   57   58   59   60   61   62   63