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50   G a s , C h e m i c a l , a n d F r e e - E l e c t r o n L a s e r s     Chemical Lasers    51


                                 HF laser                     DF laser
                                                                           10
                                                                          9
                                                                          8
                                                      V = 3              7
                                                                      J = 6
                                              8                            10
                                             7                            9
                                            6                             8
                        V = 2                         V = 2
                                            5                            7
                                         J = 4                        J = 6
                                              8                            10
                                             7                            9
                                            6                             8
                        V = 1                         V = 1
                                            5                            7
                                         J = 4                        J = 6
                                              8                            10
                                             7                            9
                                            6                             8
                        V = 0                         V = 0
                                            5                            7
                                         J = 4                        J = 6
                      Figure 3.4  Energy-level diagram for representative laser transitions for
                      hydrogen fluoride (HF) and DF lasers.


                         For the HF and DF P branch, the corresponding transition ener-
                      gies to the first order are as follows:

                       ω      = 4138.73 – 180.1ν + (2J – 1)B  + higher-order terms   (3.7a)
                         photon                      e
                       ω  photon  = 3000.36 – 94.7ν + (2J – 1)B  + higher-order terms   (3.7b)
                                                    e
                      The corresponding wavelength range for HF CW lasers is 2.6 to 3.0
                      µm, whereas for DF lasers, it is 3.6 to 4.0 µm. Pulsed devices have a
                      slightly wider range. The primary motivation for DF use as opposed
                      to HF is to avoid atmospheric water band absorption. In the absence
                      of deliberate line selection approaches, HF and DF devices usually
                      lase simultaneously on multiple v-J transitions; Figs. 3.5 and 3.6 show
                      typical spectra of HF and DF CW lasers, respectively. Atmospheric
                      absorption information at these wavelengths can be found in Zissis
                              9
                      and Wolf.
                      3.3.2  Small Signal Gain
                      The general expression for small signal gain in a laser can be expressed
                      as follows:
                                                      2
                                γ(ν) = {[N  – N (g /g )] × λ /(8πt spont )}g(ν)   (3.8)
                                            L
                                       U
                                              U
                                                 L
                      where  N  = upper-level number density
                              U
                             N  = lower-level number density
                              L
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