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CHAPTER 5   Hybrid CO 2 EOR Using Low-Salinity and Smart Waterflood  123


          Ca 2þ  might modify the wettability additionally toward  Because the role of clay is important to simulate
          more water-wetness. Another study of Dang, Nghiem,  the wettability modification effect following LSWF
          Chen, Nguyen, and Nguyen (2014) reported more  mechanism in sandstone, the dispersed clay is addition-
          wettability modification effect with more cation  ally modeled. The reservoir model has the high uncer-
                      2þ
          exchange of Ca . The comparison between LS-CO 2  tainty in clay distribution of reservoir. Considering
          WAG process with and without calcite reaction  the different facies and clay mapping, a number of
          obviously confirms that higher recovery is obtained  geological realizations of clay distribution in reservoir
          when the calcite mineral dissolves. Higher adherence  are investigated. Considering the uncertainty, the
          of Ca 2þ  on rock by more cation exchange is observed  LS-CO 2 WAG process provides the additional oil
          because of calcite mineral dissolution. It is implied  recovery from 4.5%e9% over conventional CO 2 WAG
          that CO 2 solubility in brine might reduce the amount  process.
          of CO 2 to be miscible with oil. However, it can promote  The numerical studies (Al-Shalabi, Sepehrnoori, &
          the wettability modification of LSWF mechanism. In  Pope, 2014; Al-Shalabi, Sepehrnoori, & Pope, 2016)
          addition, the LS-CO 2 WAG overcomes the delay in  have reported the modeling of LS-CO 2 WAG process
          oil production, which is observed in CO 2 injection  in carbonate rocks based on the numerical models of
          (Kulkarni & Rao, 2005). Comparing with CGI and  LSWF and CO 2 WAG process. The LS-CO 2 WAG process
          conventional CO 2 WAG process, LS-CO 2 WAG shows  is assumed to be involved with the mechanism of LSWF
          the higher oil production rate as soon as CO 2 is  and immiscible/miscible mechanisms of CO 2 WAG. It
          injected (Fig. 5.6), which indicates the less delay in oil  adapts the modeling of LSWF mechanism as empirical
          production. Dang et al. (2014) extended the numerical  approach of wettability modification (Al-Shalabi,
          simulation of LS-CO 2 WAG process to the field-scaled  Sepehrnoori, Delshad, & Pope, 2015). Because LSWF
          assessment. Brugge benchmark field (Peters et al.  model considers only two-phase flow of oil and water,
          2010) is used for the deployment of LS-CO 2 WAG.  the empirical approach of wettability modification

                  60



                  50
                                                                     High Salinity WAG
                                                                     Low Salinity WAG
                                                                     Pure CO2 Flooding
                  40
                  Oil Rate SC (bbl/day)  30






                  20



                  10


                   0
                    200              400              600              800              1,000
                                                 Time (day)
                FIG. 5.6 Comparison of oil production rate of continuous CO 2 gas injection, conventional CO 2 water-
                alternating gas injection, and low salinityeassisted CO 2 water-alternating gas injection. (Credit: From Dang,
                C. T. Q., Nghiem, L. X., Chen, Z., Nguyen, N. T. B., & Nguyen, Q. P. (2014). CO 2 low salinity water alternating
                gas: A new promising approach for enhanced oil recovery. Paper presented at the SPE improved oil recovery
                symposium, Tulsa, Oklahoma, USA, 12e16 April. https://doi.org/10.2118/169071-MS.)
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