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                                                                    Groundwater investigation techniques  151


                             ρ ce  + e  )
                               (
                        ∆H    +  p  sat  act
                                 r
                   ET   =         sfc                  eq. 5.9
                         ⎧    γ (r  + r  )⎫
                         ⎪
                                       ⎪
                        λ ⎨ ∆    +  sfc  aero  ⎬
                         ⎩
                                       ⎭
                         ⎪       r aero  ⎪
                   where, further to the symbols applied in equation
                   5.7, ρ = density of water, λ = latent heat of vaporiza-
                   tion, c = specific heat capacity of water, r = surface
                        p                          sfc         Fig. 5.10 Sketch of the occurrence of water within unsaturated
                   resistance, r  = aerodynamic roughness.     material showing both soil grains coated with a film of adsorbed
                            aero
                     The Penman–Monteith formula is used as the basis  water and soil pores filled with capillary water.
                   for the national computerized system, morecs, the
                   United Kingdom Meteorological Office Rainfall and
                   Evaporation Calculation System (Thompson et al.  which the polar water molecules are attracted to
                   1981).  morecs provides an areal-based estimate of  the charged surfaces of soil particles. Osmosis is often
                   evapotranspiration which supplements the Penman  ignored but acts to retain water in the soil as a result
                   approach with simulation of soil water flux and a   of osmotic pressure due to solutes in the soil water.
                   consideration of local vegetation cover. The model is  This occurs particularly where there is a difference in
                   based on a two-layer soil and provides estimates of  solute concentration across a permeable membrane
                   areal precipitation (P), PE, actual evapotranspiration  such as the surface of a plant root, making water less
                   (AE), soil moisture deficit (SMD) and hydrologically  available to plants, especially in saline soils, and is
                   effective rainfall (P − AE − SMD) for 40 × 40 km grid  of importance when considering irrigation water
                   squares on a weekly basis.                  quality (Section 6.2.2).
                                                                 Capillary forces result from surface tension at
                                                               the interface between the soil air and soil water.
                   5.4 Soil water and infiltration              Molecules in the liquid are attracted more to each
                                                               other than to the water vapour molecules in the air,
                   Understanding soil water distribution, storage and  resulting in a tendency for the liquid surface to con-
                   movement is important in hydrology in predicting  tract. This effect creates a greater fluid pressure on
                   when flooding will occur and also in irrigation  the concave (air) side of the interface than the convex
                   scheduling. In hydrogeology, understanding infiltra-  (water) side such that a negative pressure head,
                   tion of water in the unsaturated zone is a necessary  indicated by −ψ (in centimetres or metres head of
                   prerequisite to quantifying groundwater recharge to  water), develops relative to atmospheric pressure.
                   the water table. The branch of hydrology dealing  The smaller the neck of the pore space, the smaller
                   with soil water and infiltration is studied in detail by  the radius of curvature and the more negative the
                   soil physicists and suggested further reading in this  pressure head. In soil physics, the negative pressure is
                   topic is provided at the end of this chapter.  often termed the suction head or tension head and
                                                               describes the suction required to obtain water from
                                                               unsaturated material such as soils and rocks of the
                   5.4.1 Soil moisture content and soil        unsaturated zone. With increasing moisture content,
                   water potential                             the larger pore spaces become saturated and the
                                                               radius of curvature of the menisci increases creating a
                   Water contained in the soil zone is held as a thin film  more positive pressure head (i.e. the suction head is
                   of water adsorbed to soil grains and also as capillary  reduced). Close to the water table, the pore space is
                   water occupying the smaller pore spaces (Fig. 5.10).  fully saturated but the pressure head is still negative
                   The main forces responsible for holding water in the  as a result of water being drawn up above the water
                   soil are those of capillarity, adsorption and osmosis.  table by the capillary effect (see Fig. 2.14). Hence, the
                   Adsorption is mainly due to electrostatic forces in  measurement of soil moisture content and pressure
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