Page 128 - Illustrated Pocket Dictionary of Chromatography
P. 128

MICROPOROUS      127


                                     COO
                           COO
                                               COO
                    COO
                                                      COO

             OOC
                                                          COO



                                                           COO
           OOC


                                                          COO
             OOC

                                                     COO
                  OOC
                                               COO
                         OOC
                                     COO
                                   Micelle



        microbore Columns that have inner diameters (ID)  <2mm are
        considered microbore columns. The packing material used in these
        columns is usually  £3mm in diameter. Flow rates are typically
        £0.2mL/min (because of the very high backpressure generated in the
        system). These systems are especially suited for LC/MS work, limited
        sample situations, or separations requiring high peak capacities. From
        an operation point of view, as the inner diameter and column length
        decrease, the sensitivity of the method increases (less dilution of the
        sample) but the difficulty of normal maintenance increases (easy to
        damage or contaminate).
        microporous Refers to polymerized resins (e.g., polystyrene-
        divinylbenzene) that form particles of a size and shape that are
        dependent on the rate of polymerization (controlled by concentration,
        addition rate, temperature, etc). The result is a porous, pressure-
        sensitive, irregularly shaped particle.
   123   124   125   126   127   128   129   130   131   132   133