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4,4 WATER PROPERTIES AND TREATMENT                                       I 5 1

                  pharmaceutical industry and silicon chip manufacturers require the greatest
                  purity in the water used.

                  4.4.2. i Heavy Metals
                      Table 4.13 lists the most commonly encountered pollutants in water;
                  however, in many industrial applications various heavy metals are frequently
                  combined in the process discharge.
                      Some heavy metals are essential to life at low concentrations but are dan-
                  gerous to animal and plant life in higher concentrations. Generally, it is the
                  free metal ion that is the most toxic; however, with Hg and Sn certain organic
                  forms have a greater toxicity.
                      The WHO, the CEN, and the Environmental Protection Agency in the
                  United States specify the maximum permissible concentrations of these metals
                  and other pollutants in the environment.
                      Due to the many variables involved, no attempt is made at this stage to
                  cover the various methods used to remove these pollutants before the water
                  is released into the environment. Table 4.14 lists the common heavy metals
                  in water.


                  TABLE 4.14 Heavy Metals

                                   Chemical
                  Constituent     formula     Problems caused

                  Antimony         Sb         Moderately toxic
                  Arsenic          As         Highly toxic, corrosive, carcinogen
                  Beryllium        Be         High toxicity, long-term effects
                  Cadmium          Cd         Highly toxic, carcinogen
                  Chromium         Cr         Compounds may be highly toxic
                  Cobalt           Co         Moderate toxic
                  Copper           Cu         Highly toxic
                  Lead             Pb         A cumulative poison
                  Mercury          Hg         Very highly toxic
                  Molybdenum       Mo         Compounds are highly toxic
                  Nickel          Ni          Highly toxic, carcinogenic
                  Selenium        Se          Highly toxic
                  Silver          Ag          Low toxicity
                  Tellurium       Te          Highly toxic
                  Thallium        Tl          Sulfates highly toxic
                  Tin             Sn          Irritation of skin, eyes, lungs, and
                                                stomach
                  Titanium        Ti          Chlorides are moderately toxic
                  Uranium         U           Toxic, insoluble in water
                  Vanadium        Va          Oxides and chlorides have a high tox-
                                                icity
                  Zinc            Zn          Moderately toxic, carcinogenic
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