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484   Industrial Wastewater Treatment, Recycling, and Reuse


          models of the individual units. The ability to include alternative operating
          strategies, bypassing entire sequences of operations and mimicking hierar-
          chical control strategies in an Aspen model, enabled development of and
          simulations with very realistic process models.


          12.3.5 Water Optimization in the Bayer Process: Water
          Integration
          Deng and Feng (2009) analyzed the water system of an entire alumina plant
          using the methods of pinch technology and obtained optimal water regen-
          eration flow rates and contaminant concentrations targets. Based on these,
          they designed a water-using network that would achieve zero waste dis-
          charge, resulting in a freshwater saving rate of 62.7%.
             The authors looked at the operations in a water-using network
          that included losses but no reuse (Figure 12.8). Some of these are fixed-
          contaminant-load operations (e.g., washing, scrubbing, and extraction)
          involving mass transfer of contaminant from the source (contaminant-rich)
          to the demand (contaminant-lean) stream. These operations are designed to
          pick up a specified amount of contaminant. Other operations are fixed-flow
          rate (e.g., boiler, cooling tower) that do not involve mass transfer and the
          main concern is flow rate.
             The authors tabulatedlimiting data for all operations as fixed-contaminant-
          load operations. This yielded the flow rates required to remove a specified
          contaminant load, given the inlet and outlet concentration and water loss.



                                           Loss of water (Y1 t/h)
                         X1 t/h
                                Process I
                         X2 t/h            Loss of water (Y2 t/h)
                                Process II
                   Fresh
                                           Loss of water (Y3 t/h)
                   water  X3 t/h
                                Process III                Wastewater
                    X                                         for
                                                            treatment
                         X4 t/h            Loss of water (Y4 t/h)
                               Process IV


                         X5 t/h            Loss of water (Y5 t/h)
                                Process V
          Figure 12.8 Initial water-using network for a process industry.
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