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Measurement techniques: thermocouples 271
             compensation.  Instead  of  the  bridge  circuit  of   thermocouple.  It  can  be  seen that  for tempera-
             Figure  14.31  it  is  possible  to  arrange  the  cold   tures in the range -50  "C to 400 "C the character-
            junction correction after the input amplifier. This   istic is approximately linear. The commonly used
             has  the  advantage  that  the  voltage  levels  being   base metal thermocouples are types E, J. K, and
             worked with may be of the order of several volts   T. Of these J and K are probably the most usual
             amplitude  instead  of  a  few millivolts, making  it   ones. They have a high e.m.f. output, and type K
             easier to get a higher degree of accuracy for com-   is reasonably resistant to corrosion. Type T has a
             pensation. Figure 14.33(b) shows a block diagram   slight advantage, where the temperature measure-
             of such an arrangement. Thermocouple input cir-   ment points are very remote from the instrumen-
             cuits  are  available  as  encapsulated  electronic   tation, that as one conductor is copper the overall
             modules. These modules contain  input  amplifier   resistance  of  the  circuit  can  be  lower  than  for
             and  cold junction  compensation.  Siiice  the  cold   other types. Type N is a newer thermocouple that
            junction  consists of  the input  connections of  the   can  be  used  as  an alternative to  type  K.  Table
            module,  the  coiinections  and  the  cold junction   14.14 shows  some commercially  available  thes-
             sensor can be  accurately maintained  at the same   mocouples  which  are  not  currently  covered  by
             temperatnre  by  encapsulation,  giving very  accu-   British Standards.
             rate  compensation.  These  modules  can  be  very
            versatile. Many are available for use with any of   14.5.2.2  Preciotts iuetal thernzocozyles
             the  normal  thermocouples.  The  cold  junction
            compensation is set to the thermocouple in use by   Thermocouples types B:  R, and S clearly carry a
            connecting  a  specified value  resistor  across  two   considerable cost penalty  and  normally are only
            terminals of the module. Where the thermocouple   used when essential for their temperature range or
            instrument is based on a microcomputer the cold   their relatively high resistance to chemical attack.
            junction  compensation can be  done by  software,   Their temperature top limit is 1500  "C for continu-
            the  microcomputer  being  programd  to  add  the   ous use or 1650 "C for intermittent, spot reading,
            compensation value to the thermocouple output.   applications. This compares with 1100 "C continu-
            In all electronic equipment for thermocouple signal   ous and 1300°C intermittent for type K.
            processing  the  location  of  the  sensor  for  cold   Errors in  type  R  and  S thermocouple readouts
            junction temperature sensing is critical. It must be   result from strain. Contamination, and rhodium drift.
            very close to the cold junction terminals and pre-   The  effect  of  strain  is  to  reduce  the  e.m.f.
            ferably in physical contact with them.    resulting  in  low  readings.  The  effect  of  strain
                                                      may be removed by annealing the thermocouple.
                                                      Installations  should  be  designed  to  minimize
             14.5.2  Thermocouple materials
                                                      strain on the thermocouple wires.
            Broadly, thermocouple materials divide into two   Contamination  is  by  far  the  most  common
            arbitrary groups  based  upon  cost  of  the mater-   cause of thermocouple  error and often results in
            ials, namely, base metal thermocouples and pre-   ultimate mechanical failure of the wires. Elements
            cious metal thermocouples.                such as Si: P, Pb, Zn, and Sn combine with plat-
                                                      inum  to  form  low  melting  point  eutectics  and
                                                      cause rapid embrittlemeiit and mechanical failure
            14.5.2.1  Bme metal tlzermocozyles
                                                      of the thermocouple  wires. Elements such as Ni.
            The  most  coniionly  used  industrial  thermo-   Fe, Co, Cr, and Mn affect the e.m.f. output of the
            couples  are  identified  for  convenience  by  type   thermocouple  to  a  greater  or  lesser degree, but
            letters. The main types, together with the relevant   contamination  by these elements does not  result
            British  Standard  specification  and  permitted   in  wire  breakage  and  can  only  be  detected  by
            tolerance  on  accuracy,  are  shown  in  Table   regular  checking of  the accuracy of the thermo-
             14.13. Also  shown  are their  output  e.m.f.s with   couple. Contamination can be avoided by careful
            the cold junction at 0 "C. These figures are given   handling  of  the  thermocouple  materials  before
            to  indicate  the  relative  sensitivities of  the  var-   use and by the use of efficient refractory  sheath-
            ious  couples. Full tables  of voltages  against  hot   ing. Care should be taken to prevent dirt. grease.
            junction  temperatures are published in BS 4937.   oil,  or  soft  solder coming into contact  with  the
            The  standard  also  supplies  the  equations  gov-   thermocouple wires before use. If the atmosphere
            erning the thermocouple e.m.f.s for convenience   surrounding  the  thermocouple  sheath  contains
            for  computer  programming  purposes.  These   any metal vapor, the sheath must  be impervious
            equations  are  essentially  square  law;  however,   to such vapors.
            provided  a  thermocouple  is  used  at  tempera-   Rhodium  drift  occurs  if  a  rhodium-platinum
            tures  remote  from  the  neutral  temperature  its   limb is maintained in air for long periods close to
            characteristic is  very nearly  linear.  Figure  14.34   its  upper  temperature  limit. Rhodium  oxide  will
            shows a  plot  of the  characteristic for a  type  K   foim  and  volatilize, and  some of  this  oxide can
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