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Measurement techniques: thermocouples 273


























                                     I     I     I     I
                  -8    -4     0     4     8    12    16
                                Thermocouple EMF mV
             Figure 14,34  Type K thermocouple characteristic.

             Table 14.74 Thermocouples commercially available but not covered by British Standards (composition and accuracy to be
             agreed with manufactuer).

             Tipe   Coridiictors              Output for indicated       Service  teriiperatwe
                    (positive conductor first)   temperature (cold jiazction ut 0 'C)   (~u.Y. irztermirterzt senice)
                                                                                        -~
             W      Tungstenhngsten: 26%      34.1 mV at 2000°C          20-23OO'C  (1600°C)
                    rhenium
             w5     Tungsten: 3% Rhenium/     32.404 mV  at 2000 "C
                    tungsten: 26% rhenium
             w3     Tungsten: 3% rhenium/     35.707mV at 2000 "C        (W, suitable for hydiogen
                    tungsten: 25% rhenium                                atmosphere)
                    Tungstenlmolpbdenum
                    Rhodium: iridium/rhodium   Typically 6.4mV at  1200°C
                    Iron/eold: nickel/chromium                           1 to 2 300K
                    Iron:-gold/silver                                    1 to 2 300K


            need  to  be  interchangeable  with  other  types  of   14.5.3.3  i2~izerLrl-iiiszilnted tlzerrnocoi~ples
            temperature  measurement  equipment, are avail-
            able sheathed  in steel  or stainless  steel designed   Probably  the  most  versatile  format for thermo-
            for direct insertion into process vessels or for use   couples  is  the  mineral-insulated  (MI) construc-
            in a thermometer pocket. Figures 14.36(a) and (b)   tion.  In  this  form  the  thermocouples  are made
            show  typical  insertion  probes.  Where  thermo-   from mineral-insulated  cable  similar  in  concept
            couples  are  to  be  immersed  in  very  corrosive   to the MI cable used for electrical wiring applica-
            process  fluids  or  into  very  high  temperature   tions. It differs,  however,  in that the conductors
            locations  they  are  available  constructed  in   are  of  thermocouple  wire  and  the  sheath  is
            ceramic sheaths as in  Figure  14.36(c). Sheathed   usually  stainless  steel.  The  insulation.  however,
            thermocoaples. especially the ceramic ones, suffer   is  similar, being  in  the form of finely  powdered
            from  a  slow  response  time,  typically  a  minute   and  densely  compacted  ceramic, usually  alumi-
            or  more.  However.  the  locations  where  they   num  oxide  or  magnesium  oxide.  Figure  14.36
            are  essential  for  their  mechanical  properties   shows MI thermocouples at (d). (e). and (f).
            are usually  in  heavy  plants  where  temperatures   They  are  available  in  diameters  from  1  milli-
            do not normally move fast in any case     meter up to 6 millimeters  and can be  sapplied in
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