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Measurement techniques: radiation thermometers 279
              In  practice  a  sighting  hole  in  a  furnace  will   portional  to  the  fourth  power  of  the  tempera-
             radiate  as  a  blackbody  if  the  furnace  and  its   ture Kelvin of the radiator.
             contents are in thermal equilibrium and provided
             it does not contain a gas or flame which absorbs
             or radiates preferentially in any wavelength band.   14.6.1.2  The distribution  of energy in the
             However,  the  radiation  from  the  sighting  hole   spectizan:  Wien 's laws
             will only be blackbody radiation provided every-   When a body is heated it appears to change color.
             thing in the furnace is at the same temperature.   This is because the total energy and distribution
             When  all objects in the furnace are at the same   of  radiant  energy  between  the  different  wave-
             temperature  all  lines  of  demarcation  between   lengths  is  changing  as  the  temperature  rises.
             them will disappear. If a cold object is introduced   When the temperature  is about 500°C the body
             to the furnace it  will  be  absorbing more  energy   is just  visibly red.  As  the temperature  rises,  the
             than it is radiating; the rest of the furnace will be   body  becomes dull red  at  700"C, cherry  red  at
             losing  more  radiation  than  it  receives.  Under   900°C. orange at  1100°C. and finally white hot
             these conditions the radiation  will  no  longer be   at temperatures above 1400  "C. The body appears
             blackbody radiation  but will be dependent upon   white  hot  because  it  radiates  all  colors  in  the
             the emissivity of the furnace walls.     visible spectrum.
                                                        It is found that the wavelength of the radiation
             Prevost's theory of  exchanges  Two bodies A and   of  the  maximum  intensity  gets  shorter  as  the
             B in a peirfectly heat-insulated  space will both be   temperature  rises.  This  is  expressed  in  Wien's
             radiating and both be absorbing radiation. IfA is   displacement law:
             hotter than B it will radiate more energy than B.
             Therefore B will receive more energy than it radi-   A,T   = constant
             ates and consequently its temperature will rise. By   =2898ym.K          (14.26)
             contrast  body  A  will  lose more  energy by  radi-
             ation than it receives so its temperature will fall.   where A,   is the wavelength corresponding to the
             This process will continue until both bodies reach   radiation  of  maximum  intensity.  and  T is  the
             the  same  temperature.  At  that  stage  the  heat   temperature Kelvin. The actual value of the spec-
             exchanged  from  A  to  B  will  be  equal  to  that   tral  radiance  at  the  wavelength  A,   is  given  by
             exchanged from B to A.                   Wien's second law:
               A  therimometer placed  in  a vessel to measure
             gas  temperature  in  that vessel will; if  the  vessel   LA, = constant x  T5   (14.27)
             walls  are  cooler  than  the  gas,  indicate  a  tem-
             perature    than the gas temperature because   where LA, is the maximum value of the spectrai
             it will radiate more heat to the vessel walls than   radiance at any wavelength, Le., the value of the
             it receive:; from them.                  radiance at A,,   and Tis the temperature Kelvin.
                                                      The constant does not have the same value as the
             Blackbo~+  radiation:  Stefan-Boltzmann   lw   constant  in  equation  (14.26). It  is  important to
             The total power of radiant flux of all wavelengths   realize that  it  is  only the maximum  radiance  at
             R emitted into the frontal  hemisphere by  a unit   one particular  wavelength which is proportional
             area of a perfectly black body is proportional to   to  T';  the  total radiance  for  all wavelengths is
             the fourth power of the temperature Kelvin:   given by the Stefan-Boltzmann  law, Le.. it is pro-
                                                      portional to T4.
                 R = GrP                     (14.25)    Wien deduced  that the spectral concentration
                                                      of radiance, that is, the radiation emitted per unit
             where CT  is the Stefan-Boltzmann  constant, having   solid angle per unit area of a small aperture in a
             an accepted value of 5.670  32  x  lo-'  W  m-? K-4,   uniform temperature enclosure in a direction nor-
             and 7 is the temperature Kelvin.         mal  to  the  area  in  the  range  of  wavelengths
               This  law  is  very  important,  as  most  total   between A  and A + SA is LA. SA where
             radiation  thermometers  are based  upon  it.  If  a
             receiving  element  at  a  temperature  TI  is                            (14.28)
             arranged  so  that  radiation  from  a  source  at  a
             temperature  T2  falls upon it. then it will  receive
             heat  at the rate  of  aT;> and emit  it  at a rate of   where Tis the temperature Kelvin, and C1 and C,
             UT;. It will,  therefore,  gain  heat  at  the  rate  of   are constants. This formula is more convenient to
             G~(T: - Tf). the temperature  of  the receiver is   use and applies with less than 1 percent deviation
                       If
             small  in  comparison  with  that  of  the  source,   from  the  more  refined  Planck's  radiation  law
             then  Tf  may  be  neglected  in  comparison  with   used  to  define  IPTS-68  provided  AT  < 3 x
             T;> and  the  radiant  energy  gained  will  be  pro-   103rn. K.
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