Page 541 - Instrumentation Reference Book 3E
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524  Nuclear instrumentation technology

                                                      vary enormously, from the small NaI (Tl) (this is
                                                      the way of writing "sodium  iodide with thallium
                                                      additive")  crystal  used  in  medical probes  up to
                                                      tanks of liquid scintillator of thousands of cubic
                                                      meters used in cosmic ray research.
                                                        The  selection of  a  suitable material-some  of
                                                      whose characteristics are given in Tables 22.5 and
                                                      22.64epends  on a number of competing factors.
                                                      No  material  is  perfect  so comproinises must  be
                                                      made in their selection for particular purposes.

                                                      22.2.2.1  Inorgaizicscintillators
                                                      NaI (TI) is still after many years the best gamma-
                                                      and  X-ray  detector  actually  available,  yet  it  is
                                                      very hygroscopic and must be completely sealed
                                                      from moisture.  It is sensitive to shock, except in
                 0.1     0.3  0.5  0.9   2   4   6  8 10
                                                      the new form  of extruded  NaI (Tl) called Poly-
                         Maximum beta energy (MeV)    scin, developed by Harshaw, and it is expensive,
             Figure 22.3  Transmission  of thin windows.   especially  in  large  sizes.  Its  light  output  is,  in
                                                      general, proportional to the energy of the photon
             converter  (generally a  photomultiplier)  and  the   absorbed, so that the pulse height is a measure of
             electronic amplifier; we consider the wide variety   the energy of the incident photon and. when cali-
             of each of these items which are available today.   brated with photons of known energy, the instru-
               The scintillator can consist of a single crystal of   ment  can  be  used  as a  spectrometer.  The decay
             organic or inorganic material;  a plastic fluor, an   lifetime of NaI (Tl) is relatively slow, being about
             activated glass, or a liquid. Shapes and sizes can   230 ns, although NaI without any thallium when


             Table 22.4  Transmission of thin windows
             Nuclide     Max. energy    Percentage transinission fov window thickness of
                         E,,,,  (MeV)
                                        30 mg/cm2      20 mgtcm'      7 mg/cm2      3 mdcm'
             '4c         0.15            0.01           0.24          12            40
             32P         1.69           72             80.3           92            96




             Table 22.5  Inorganic scintillator materials
             Material'   Density  Refractive  Light   Decuji   Wuwlength   Operuting   Hygroscopic
                       (g/cm3)  index   outpui     constunt   ofn~u.~i~~~i~n~ teinyerutirre
                              (n)     (% anthracene)  (s)     emission (nm)  ("C)

             NaI (Tl)   3.67   1.775   230           0.23 x   413         Room      Yes
             NaI (pure)   3.67   1.775   440         0.06 x   303         ~         Yes
             CsI (TI)   4.51   1.788   95             1.1 x  10-6   580   Room      No
             CsI (TI)   4.51   1.787   150-190       0.65 x   420         Room      Yes
             CsI (pure)   4.51   1.788   500          0.6 x   400         ~         No
             CaFz (EU)  3.17   1.443   110             1 x  10-6   435    Room      No
             LiI (EU)   4.06   1.955   75             1.2 x  10-6   475   Room      Yes
             CaWO,     6.1    1.92     36              6 x    430         Room      No
             ZnS (Ad   4.09   2.356   300             0.2 x  10-6   450   Room      No
             ZnO (Ga)   5.61   2.02    90             0.4 x  10-9   385   Room      No
             CdWO4     7.90                        0.9-20  x   530        Room      No
             Bi4Ge;Olz   7.13   2.15                  0.3 x   480         Room      No
             CsF       4.64   1.48     40             5 x  lo-"   390     Room      No
             1.  The deliberately added impurity is given in parentheses.
             2.  Light output is expressed as a percentage of that of a standard crystal of anthracene used  iii the  same geometry.
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