Page 155 - Lignocellulosic Biomass to Liquid Biofuels
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130   Lignocellulosic Biomass to Liquid Biofuels


                                                              World total
             Billion litres
                                                     127.7 billion litres
              120
                      Hydrotreated vegetable oil (HVO)
              100     Biodiesel
                      Ethanol
               80


               60

               40


               20

               0
                  2004  2005  2006  2007  2008  2009  2010  2011  2012  2013  2014
          Figure 4.1 Ethanol, biodiesel, and HVO (Hydrotreated Vegetable Oil) Global
          Production, 2004 14 [9].


          agricultural residues are produced world-wide annually as agro-forestry
                                                            6
                                      6
          by-products and that 1376 3 10 t cellulose and 848 3 10 t hemicellulose
          are produced globally every year. Furthermore, it has been estimated that
                   6
          1300 3 10 t of food are wasted every year, corresponding to one-third of
          the  food   globally  produced  for  human   consumption  [16,17].
          Lignocellulosic biomass can be considered the most abundant carbon-
          neutral renewable source, which can decrease CO 2 emissions and atmo-
          spheric pollution. Furthermore, its major component, the cellulose, is the
          strongest potential candidate for the substitution of petroleum-based poly-
          mers because of its ecofriendly properties such as renewability, biocompat-
          ibility, and biodegradability [18].
             Table 4.1 shows the comparison of various biodiesel lignocellulosic
          sources grown worldwide in terms of oil yield, oil content, land area use,
          productivity, and price.
             The development of lignocellulosic biomass conversion to biodiesel
          and polymers still remains a big challenge due to the technical and eco-
          nomic obstacles [12,15,19] mostly related to the biomass recalcitrance
          stemming from the barriers naturally developed to avoid the degradation
          from natural infections. The future of second-generation biofuel produc-
          tion will be critically affected by the price of the oil, as well. It is
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