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CHAPTER 3

              Bioconversion of lignocellulosic

              biomass to bioethanol

              and biobutanol


                                                         1
                               1
              Alessandra Verardi , Catia Giovanna Lopresto ,
                             2
                                                 1
              Alessandro Blasi , Sudip Chakraborty and Vincenza Calabrò 1
              1
              Department of Computer Engineering, Modeling, Electronics and Systems Engineering (DIMES),
              University of Calabria, Rende, Italy
              2
              ENEA—Italian National Agency for New Technologies, Energy and Sustainable Economic Development,
              Energy Technologies Department, Research Centre of Trisaia, Rotondella, Italy
              Contents
              3.1 Introduction                                              67
              3.2 Suitable strains and their productivity                   71
                 3.2.1 Bioethanol                                           73
                 3.2.2 Biobutanol                                           78
              3.3 Enzymatic hydrolysis                                      80
                 3.3.1 Enzymatic hydrolysis of lignocellulosic biomass      80
                 3.3.2 Traditional downstream purification                  83
                 3.3.3 Possibilities of application of membrane in bioethanol production  83
                 3.3.4 Final comments                                       89
              3.4 Simultaneous saccharification and fermentation            89
              3.5 Effect of fermentation inhibitors                         96
                 3.5.1 Furfural and 5-hydroxymethylfurfural                 97
                 3.5.2 Weak acids                                           100
                 3.5.3 Phenols                                              104
                 3.5.4 Interaction effects                                  105
                 3.5.5 Other inhibitor compounds                            106
                 3.5.6 Strategies for minimizing inhibitor effects          106
              3.6 Conclusion                                                108
              References                                                    108
              Further reading                                               124





              3.1 Introduction
              For the last 25 years domestic sources of fuels, need of renewable energy,
              and chemicals have become highly significant [1]. Bioethanol has the

              Lignocellulosic Biomass to Liquid Biofuels   © 2020 Elsevier Inc.
              DOI: https://doi.org/10.1016/B978-0-12-815936-1.00003-4  All rights reserved.  67
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