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28                  Low-Temperature Energy Systems with Applications of Renewable Energy

            The results of Example 3 are summarized in Table 1.3.
            Summarizing: On an overall energy basis, the heat pump COP is 2.5 (i.e., 350/140);
         that is, 2.5 times more energy was delivered to the heated space in the form of heat than
         was needed to drive the heat pump. However, on an exergy basis, the COP is just 0.389
         (i.e., 54.51/140). That is, of the 140 kW of exergy spent to drive the heat pump, only
         54.51 kW of exergy was actually delivered to the heated space, i.e., 38.9%. The high
         loss in the throttle suggests that improvement may be achieved by staging the throttling
         into 2- or 3-stages combined with staged compression with interstage cooling. An
         alternative approach would be to replace the throttle with a total-flow expander capable
         of producing power that could partially offset the work needed to drive the
         compressor; this option is left for the reader to explore (see Problem 4 at the end of
         the chapter). The losses in the condenser might be reduced by lowering the superheat
         at the compressor outlet (a consequence of staged compression) and lowering the
         average temperature difference between the R152a and the heating fluid. This last
         modification would however require an increase in the area for heat transfer and a
         more costly heat exchanger.



         1.6   Working fluids for refrigeration and heat pumps
               systems

         1.6.1  Antifreeze solutions
         Antifreeze is a mixture that remains a liquid when used, for example, in the pipeline
         network of a buried collector coil. The evaporator of the heat pump is a suitable appli-
         cation for antifreeze mixtures. But it is necessary to take into account that the hydraulic
         evaporator resistance is increased as well. When an antifreeze mixture goes through a
         pipe, the hydraulic resistance is determined by taking into consideration the viscosity
         coefficient. Furthermore, it is important to note that the use of antifreeze in some con-
         centrations does not guarantee that it will not freeze at significantly negative ambient
         temperatures. Thus, the buried pipe coil of the soil heat exchanger should be laid below
         the frost line.
            Here are some antifreeze mixtures that may be considered.

                  Table 1.3 Exergy destruction in heat pump components, Example 3.

                   Component    Exergy destroyed, kW  Percent of total, %
                   Compressor   18.99               23.2
                   Condenser    11.12               13.6
                   Throttle     44.45               54.4
                   Evaporator   7.15                8.75
                   Total        81.71               100
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