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28   Methods for Monitoring and Diagnosing the Eficiency of Catalytic Converters



                The objective  of this book  is to serve as a  compendium of the literature and  the methods
                existing in  the field of monitoring of catalytic converters only, with a particular  emphasis on
                patent disclosures. Of course, some selected non-patent literature is also included.

                The book is divided in four  chapters. Each of the chapters 1 to 3 reflects a group of methods
                for the monitoring of catalytic converters.

                Chapter  1 comprises methods that use oxygen or airlfuel ratio (A or lambda) sensors upstream
                and downstream of the converter in order to detect degradation of the converter.

                Chapter 2  comprises methods that use temperature measurements of the exhaust gases inside
                or outside the catalytic converter in order to detect degradation of the converter.

                Chapter 3 comprises all other methods not covered by the methods of chapters 1 and 2. Mostly
                this chapter comprises direct methods of diagnosis of catalytic converters by means of HC, CO
                or NO,  sensors.





                CARB       TI,EV          Catalytic converter conversion rate HC<60-80%  at  steady
                           (models 1994,   state condition
                           1995)
                           Non-I, E Kv    Catalytic converter caused deterioration of the HC-results
                CARB       (HC            by 0.4 g/mile  (=IS x 0.25 g/mile)
                           0.2 5 g/inile)
                                                                                  ~~
                                          Main  cataZvfic  converfer:   decline  of  the  HC-
                                          conversion rate in the FTP-Test  to SO-60% (i.e. final raw
                                          emission > 40-50% of raw emission
                           LEVs           Snrall  vol.  Catalytic  com)erter:  decline  of  the  HC-
                CARB       (NMOG          conversion rate in the FTP-Test  by 4040% in comparison
                            0.125 g/mile)   to the value at 4000 miles (6400 km) (also valid for large
                                          primary  catalytic  converters  if  monitored  together  with
                                          downstream substrate)
                                          defective front converters must be separately detected
                                          monitoring of RHC with regard to HC-conversion rate and
                                          heating function
                Federal                   Catalytic converter  caused  deterioration  of  the HC FTP-
                OBD                       results by 0.4 @mile (=I  .5 x 0.25 g/mile or HC FTP-result
                Regulation                > 0.6 g/mile)




                Table 6: Requirements OBD I I catalytic converter monitoring (Malfunction Criteria)
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