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36    Cha pte r  T w o


                    material. Another hypothesis is that the dispersed polymer particulates may serve as
                    reinforcements, arresting microcrack propagation and increasing toughness of binders.
                    The typical trend that can be observed from review of polymer modification works,
                    however, is that not many polymers used currently improve low-temperature failure
                    properties. This may be attributed to the fact that until recently there has been no simple
                    technique to measure the brittle failure of asphalt, and also to the fact that none of the
                    used binder specifications address the brittleness of asphalt in a rational and fundamental
                    form. These issues did not encourage many polymer modifier producers to concentrate
                    on designing a modifier to mainly enhance low-temperature failure properties.
                       Figure 2-8(b) depicts failure plots for an asphalt before and after modification with
                    crumb rubber at 10 percent (CRM1) and 20 percent (CRM2) concentration by weight of
                    total binder. The effect of the CRM is similar to the polymer modification with respect to
                    the strain at failure values; higher strains are observed at low temperatures but similar
                    strains are observed as the flow region is reached by the binders. The effect also represents
                    a shift of the failure curve along the temperature scale toward lower temperatures. The
                    shift is larger for the higher CRM content. The stresses at failure, however, show a trend
                    different from the polymer modification. The CRM results in stress values that are
                    significantly higher than the unmodified asphalt at all temperatures. This behavior can
                    be attributed to the reinforcing effect of the rubber particles. The crumb rubber particles
                    do not dissolve in asphalt; the particles maintain their integrity and tend to swell in
                    asphalts resulting in effective volumes that are larger than their initial volume (Bahia
                    and Davies 1994; Chehoveits 1982). It is speculated that the swelling results in selective
                    absorption and/or adsorption of certain components of the asphalt. Such interactions
                    are expected to reinforce the matrix of the binder and result in higher strength, as
                    observed in the figure. The increase in strain and stress at failure is favorable for paving
                    grade asphalts, particularly when it is not accompanied by an increase in stiffness.

                    Effects of Modification on the Superpave Grading Properties
                    The Superpave performance grading (PG) system was developed to evaluate binder
                    properties at specific temperatures with specific testing systems (Anderson and
                    Kennedy 1993; Anderson et al. 1994; McGennis 1995). The AASHTO MP1 procedure
                    includes details of testing and grading of binders. Figure 2-9 is a schematic describing






















                    FIGURE 2-9  The Superpave grading system.
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