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Modeling of Asphalt Binder Rheology and Its Application to Modified Binders      31


                                                            Reference


                                     Terrel and   Epps 1989   Peterson  Romine et al.   Moratzai and   Moulthrop   McGennis  Isacsson and   Lu 1995  Banasiak and   Geistlinger



                Modifier                        1993    1991      1993    1995            1996
                Thermoplastic       X        X       X       X         X      X      X
                Polymers
                Thermoset Polymers  X        X       X       X         X      X      X
                Fillers/Reinf. Agents/  X    X       X       X         X      X      X
                Extenders
                Adhesion Promoters  X                X       X         X      X      X
                Catalysts or Chemical   X    X       X       X         X      X      X
                Reaction Modifiers
                Aging Inhibitors    X        X       X       X         X      X      X
                Others              X                X       X         X
                Total number of     -        46      -       82        48     31     62
                existing brands or                           (27 ASA)
                types

               ASA: Antistripping additives

               TABLE 2-2  Recent Surveys of Asphalt Modifiers

                    dissolve in the asphalt. The modifiers range from organic to inorganic materials, some of
                    which react with the asphalt while others are added as inert fillers. The modifiers generically
                    vary in their specific gravity as well as other physical characteristics. They are expected to
                    react differently to environmental conditions, such as oxidation and moisture effects.
                       Not all these types of modifiers are being currently used. The frequency of use varies
                    significantly depending on marketing of the modifiers, experience of contractors and
                    agencies, and cost. In a survey conducted in 1997, state highway agencies indicated that
                    polymer modifiers are among the most widely known and used in practice. Table 2-3
                    depicts the results of the survey (Bahia 1998b).
                       Table 2-3 shows that the elastomeric polymer styrene-butadiene-styrene (SBS) is
                    the most frequently used to target a variety of distresses among which permanent
                    deformation is the most common. As indicated in Table 2-3, many agencies did not
                    indicate the specific target distress for which they are using the modifier.


               Critical Properties of Modified Asphalts

                    Effects of Modification on Viscoelastic Properties
                    Measuring properties of modified binders has in general followed the testing technology
                    used for unmodified asphalts but in many specifications expanded to capture some
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