Page 118 - Modeling of Chemical Kinetics and Reactor Design

88 Modeling of Chemical Kinetics and Reactor Design

The result shows that –182,355 J/gmol CO must be removed. The
2
results of the ENTHALP1 computer program (S.I. units) for the heats
of reaction at 298 K and 723 K respectively are shown in Table 2-2.

Example 2-3
Using the standard heats of formation of the reaction components,
calculate the standard heat of reaction and the heat of reaction at
system temperature of 350°C and 1 atm. The reaction is:

α A + α B → α C + α D
1 2 3 4
The system temperature T = 623 K
Number of components n = 4
=
Reaction coefficients α = 1, α 2, α = 1, α = 0
3
1
4
+
2
d
C =+ ×10 −2 T c ×10 −5 T + ×10 −9 T 3 cal
a b
p
gmolK

Table 2-2
The standard heat of a chemical reaction calculation:
aA + bB → cC + dD