Page 12 - Modeling of Chemical Kinetics and Reactor Design
P. 12
Glossary 899
References 908
CHAPTER TWELVE
Safety in Chemical Reaction Engineering.................................... 910
Introduction 910
Hazard Evaluation in the Chemical Process Industries 911
Hazard Assessment Procedures 916
Thermal Runaway Chemical Reaction Hazards 919
The φ-Factor 920
Onset Temperature 923
Test Instruments 926
Two-Phase Flow Relief Sizing for Runaway Reaction 950
Vent Sizing Methods 963
Discharge System 973
Inherently Safe Plants in Reactor Systems 984
Hazard and Operability Studies (HAZOP) 991
Glossary 1010
References 1018
Appendix 1022
CHAPTER THIRTEEN
Scale-Up in Reactor Design .......................................................... 1034
Introduction 1034
Development and Scale-Up of Reactors 1036
Similarity Criteria 1037
Scale-Up in Relation to Various Factors 1037
Heat Effect 1038
Coefficients of Process Stability 1039
Dimensional Analysis and Scale-Up Equations 1040
Mathematical Modeling 1044
Scale-Up of a Batch Reactor 1047
Heat Transfer Model 1057
Jacket Zoning of a Batch Reactor 1065
The Outlet Temperature of a Scaled-Up Batch System 1070
Aspect Ratio (R) in Jacket Zoning and Scale-Up of a
Batch Reactor 1074
Nomenclature 1079
References 1080
Nomenclature ................................................................................... 1082
Index .................................................................................................. 1089
About the Author ............................................................................ 1096
xii