Page 7 - Modeling of Chemical Kinetics and Reactor Design
P. 7
Contents
Preface ................................................................................................. xiii
Introduction ........................................................................................xvii
CHAPTER ONE
Reaction Mechanisms and Rate Expressions ................................ 11
Introduction 1
Typical Reaction Mechanisms 5
Reaction Mechanisms 8
Elementary and Non-Elementary Reactions 9
Types of Intermediate 10
The Arrhenius Equation and the Collision Theory 12
Transition State Theory 15
Chain Reactions 16
Catalytic Reactions 21
Guidelines to Formulating Reaction Mechanism 32
Testing Kinetic Models 34
Chain Length 37
References 58
CHAPTER TWO
Thermodynamics of Chemical Reactions ....................................... 59
Introduction 59
Chemical Equilibrium 60
Criteria for Equilibrium 63
Reaction Equilibrium 64
Ideal Gas Mixtures 65
Real Gases—Ideal Gaseous Solutions 65
Real Gases 67
Liquid State 69
Determining the Fugacity and the Fugacity Coefficient 70
Partial Molar Quantities 72
Effect of Temperature on the Equilibrium Constant 74
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