Page 8 - Modeling of Chemical Kinetics and Reactor Design
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Heats of Reaction 75
Heat Capacities of Gases 80
Heats of Formation 80
References 93
Appendix 94
CHAPTER THREE
Reaction Rate Expression ................................................................ 109
Introduction 109
Reaction Rate Equation 110
Reaction Orders 114
Determining the Order of Reactions 116
Empirical Rate Equations of the nth Order 129
Method of Half-Life t 130
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Parallel Reactions 134
Homogeneous Catalyzed Reactions 137
Autocatalytic Reactions 138
Irreversible Reactions in Series 140
First Order Reversible Reactions 146
Second Order Reversible Reactions 150
General Reversible Reactions 151
Simultaneous Irreversible Side Reaction 152
Pseudo-Order Reaction 154
Practical Measurements of Reaction Rates 155
Regression Analysis 171
Weighted Least Squares Analysis 173
Problems and Errors in Fitting Rate Models 175
References 216
CHAPTER FOUR
Industrial and Laboratory Reactors ............................................. 218
Introduction 218
Batch Isothermal Perfectly Stirred Reactor 220
Semi-Batch Reactors 222
Continuous Flow Isothermal Perfectly Stirred Tank Reactor 226
Continuous Isothermal Plug Flow Tubular Reactor 227
Continuous Multiphase Reactors 230
Fluidized Bed System 232
Fluid Catalytic Cracking (FCC) Unit 234
Deep Catalytic Cracking Unit 235
Determining Laboratory Reactors 243
Guidelines for Selecting Batch Processes 254
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