Page 414 - Modelling in Transport Phenomena A Conceptual Approach
P. 414

394        CHAPTER 9.  STEADY MICROSCOPIC BALANCES  WITH GEN.

           On the other hand, the bulk concentration in dimensionless form can be expressed
            as


                                   CAb - CAb   =o=
                              eb =                                          (9.553)
                                  CAW - CAb       l(l-C%dt
            Substitution of Eq.  (9.552) into Eq.  (9.553) gives the Sherwood number as


                                                                            (9.554)

            Constant wall concentration

            When the wall concentration is constant, Eq.  (9.541) indicates that
                                    & = ( CAW - CA ) -
                                                       dCAb
                                    a2      CAW - cAb   dz                  (9.555)

            The variation of  CA~ as a function of  the axial position can be obtained from Eq.
            (9.524) as





                                                   -,At,
            Since the mass transfer coefficient is constant for a fully developed concentration
            profile, Eq.  (9.556) becomes

                                              cAb)
                                   ~D~(cA~ 4h(cAw - cAb)
                            dCAb
                            --  -           -      -                        (9.557)
                                                   -
                             dz           Q              D(VZ>
            The use of  Eq. (9.557) in Eq.  (9.555) yields
                                                    -
                                                      CA)
                                      &A    ~~C(CA~                         (9.558)
                                      --  -
                                      az        D(V%>
            Substitution of  Eq.  (9.5-58) into Eq. (9.542) gives
                                                                            (9.559)


            In terms of  the dimensionless variables defined by Eqs.  (9.547) and (9.548), Eq.
            (9.559) becomes
                                                                            (9.560)
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