Page 292 - MODERN ELECTROCHEMISTRY
P. 292

228  CHAPTER 3

          The result of the proton transfer is that two ions have been produced: (1) an acetate
           ion and (2) a hydrated proton. Thus, potential electrolytes (organic acids and most
          bases) dissociate  into  ions by  ionogenic, or ion-forming,  chemical  reactions  with
          solvent  molecules, in  contrast to true electrolytes,  which  often  give rise to  ionic
           solutions by physical interactions between ions present in the ionic crystal and solvent
           molecules (Fig. 3.1).


          3.2.3. An Obsolete Classification: Strong and Weak Electrolytes
              The classification into true and potential electrolytes is a modern one. It is based
           on a knowledge of the structure of the electrolyte: whether in the pure form it consists
           of an ionic lattice (true electrolytes) or neutral molecules (potential electrolytes) (Fig.
           3.2). It is not based on the behavior of the solute in any particular solvent.







































                   Fig. 3.2.  Electrolytes can be classified as (a) potential electro-
                   lytes (e.g., oxalic acid), which in the pure state consist of un-
                   charged  molecules, and  (b)  true electrolytes  (e.g.,  sodium
                   chloride), which in the pure state consist of ions.
   287   288   289   290   291   292   293   294   295   296   297