Page 40 - MODERN ELECTROCHEMISTRY

INDEX

Absolute mobility, 445 Activity coefficients (cont.)
Absorption spectroscopy, and electrolytic solu- significance, 253
tions, 338 single ionic species, a different determina-
Acetone, effect upon the solubility of argon, tion, 255
177 testable form, 257
Activation energy, various valency types, 270
diffusion at constant pressure, 688 and the zeroeth approximation, 258
“jumping,” 690 Adiabatic compressibility, for electrolytes, 62
Activities, of the solute, from data on the sol- Adler and Wainwright, introduction of molecu-
vent, 261 lar dynamics, 321
Activity coefficients Alkaline metals and hydration numbers, 144
alcohol water mixtures, 269 Aluminum chloride
chemical potentials, 252 organic complexes, structure of, 711
comparison of observed and theoretical, 347 role in the new electrochemistry of molten
concentration cells, 265 salts, 19
electrolyte as a function of hydration Apparent charge, 462
number, 295 Appleby, director, of electrochemical center, 26
evolution of the concept, 251 Aqueous solutions, and solvent dynamic simu-
experimental, 264 lations, 163
determination, 260 Aquifers, contaminated, electrochemical purifi-
finite sized ions, the theory, 277 cation, 32
function of ion size, 278 Argand diagram, 532
higher concentrations, 274, 283 dissociated electrolyte, 533
and hydration, 69 Argon, its solubility in aqueous solution, de-
individual, 266 pending upon acetone content, 177
and interionic interactions, 69 Aristotle’s ideas on solutions, 35
and ionic strength, 259, 282 Asymmetry, of the ionic cloud, 514
ion pairs, and free ions, 314 Autocorrelation function
ion size, 279 ions, 415
and ion–solvent interactions, 293 liquid argon, 417
mean, 256 Average hole, in Furth model, 640

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