Page 41 - MODERN ELECTROCHEMISTRY

xl INDEX

Bacon’s contribution to fuel cells, 2 Boltzmann equation, its linearization, 237
Batteries Booth, and the dielectric constant, near an ion,
with aluminum, 19 90
and fuel cells, from electronically conduct- Bopp
ing polymers, 560 his radial distribution function for chloride–
Bergstrom and Lindgren, IR studies on solu- water interactions, 321
tions, 75 and molecular dynamic simulation, 321
Bernal and Fowler’s seminal 1933 paper, 49 Born’s
Bewick, development of FTIR, 20 contribution to solvation heats, 121
Bhardwaj, individual activity coefficients, 266 theory of the free energy of solvation, 50
Biological systems, and water, 197 Born equation, 204, 205
Biophysics, in hydration, 192 doubts, what it represents, 206
Biowater, molecular simulation, 198 Born–Haber cycle, applied to solvation, 51
Bjerrum Boundaries, electrolyte–electrolyte, not always
association of ions, tabulated, 310 sharp, 267
and the fraction of ion pairs, 306 Boundary conditions, and diffusion processes,
and ion association, 333 386
nonaqueous solutions, distances in, 542 Breakdown potentials, as a function of conduc-
Bjerrum’s association constant, 311 tivity, 182
Bjerrum’s theory Breathing motion, in radial expansion of a
calculation of association fraction, 310 hole, 635
calculation of the minimum, 346
of ion pairing, 307 Card and Valleau, application of the Metropolis
Blast furnace: how it works, 752 Monte Carlo method, 320
Blum Center, for electrochemistry, at Texas A&M
and the dielectric constant in solutions, 328 University, 26
and the conductance theory in ionic solu- Chandrasekaran, and the mechanism of metha-
tions, 525 nol oxidation, 21
contributions to ionic solution theory, 336 Changes in volume at fusion, 627
Bockris Charge
the dielectric breakdown of water, contribu- function of distance, from the central ion,
tion to, 184 247
and dielectric constants in the double layer, ionic cloud, 246
94 interfaces, argued as inevitable, 7
his 1949 model, region around the ion, 84, moving under non-uniform field, 423
137 and the properties of interfaces, 6
and the salting in effect, 179 Charge density
Bockris and Nanis relation, distance from the central ion, function of,
diffusion, for viscous flow, 652 243
transport as a function of melting point, and Poisson’s equation, 235
680 Charge transfer,
viscous flow, 656 catalysis, 10
Bockris and Reddy, and the structure of the sol- interfacial, its significance over time, 27
vation shell, 119 reactions, disciplines involved in, 14
Bockris and Saluja Chemical potential
coordination numbers as a function of ra- variation with distance, 368
dius, 81 Chemical (or Thermal) reaction, 11
models, region near an ion, 116 Chloride, and its solvation by water, diagram-
solvation numbers as a function of radius, 81 mated, 82
solvation numbers, individual, evaluations Cloud, central, 242
for ions, 61 Cluster calculations, for water, 160