Page 45 - MODERN ELECTROCHEMISTRY

xliv INDEX

st
Entropy of translation, for ions in solution, 129 Fick’s 1 Law, 367
nd
Environments, cleaner, and electrochemistry, 25 Fick’s 2 Law, 381
Equation, differential, for the situation of po- and LaPlace transformation, 387, 419
tential near an ion, 241 Field dependence, of orbital reorientation, 578
Equations Fields, near an ion, and the compressibility of
Arrhenius, 2 water, 188
Boltzmann, 237 Field strength, and dielectric constant, 90
Born, 204 Flux
Debye–Hückel–Onsager, 518 under concentration gradients, 472
Einstein’s, 449 under field gradient, 473
Einstein–Schmolukowski, 378, 405 sinusoidal, and the treatment with LaPlace
Gibbs–Duhem, 262 transformation, 400
LaPlace, 392 Flux as a function of chemical and electrical
Leonard–Jones, 45 forces, 474
Nernst–Einstein, 456 Flux–force laws, 495
Nernst–Planck, 476 Forces, in the phenomenological treatment of
Onsager, 494 transport, 367
Planck–Henderson, 500 Fraction associated, as function of distance of
Poisson, 235, 344 closest approach, 313
Poisson–Boltzmann, 239 Franck and Evans, their 1957 work, 84
Sackur–Tetrode equation, 128 Franck and Wenn, their seminal paper of 1957,
Setchenow’s, 172 50
Tafel, 2 Frank, his theory of electrostriction, 190
Equivalent conductivity Free energies of hydration
and concentration, 434 dependence on radius, 54
of dilute solutions, tabulated, 435 how to get them, described, 53
function of rate processes, 467 Free energies of solvation, described, 53
at infinite dilution, 438 Friedman
variation with concentration, diagrammated contributions to the Mayer theory, 317
and tabulated, 437 contributions to ionic solution theory, 323
in terms of mobilities, 447 various contributions towards ion–ion inter-
Equivalent conductivity and molar conductiv- actions, 335
ity, 432 Frogs, and Galvani, 1
Error function, 394 Fuel cells
Excess free energy, and correlation functions, 326 discovered by Grove, 2
Exercises, student solution, inseparable from Bacon’s work, 2
ionic transport, 587 and metabolism, 24
on molten salts, 758 Functions, distribution, and x-ray measure-
on solvation, 213, 349 ments, 45
Expansivity, as a function of metal oxide addi- Functions of hydration, 203
tion, for liquid silicates, 740 Furth model, in molten salt theory, 638
Fused oxides, and the structure of liquid water,
Fajans, his original contributions to solvation, 53 726
Faraday, and his 1834 discovery, 2 Fused oxide systems, and the structure of
Faraday’s laws, 428 planet earth, 749
Fawcett and Tikanen Fused silica
application of dielectric constant variations its structure, 727
to MSA calculations, 329 its viscosity, 728
the MSA theory, 329 Fusion, the volume change, 613
Fermi levels, of electrons, and dielectric break- Fuxed oxide systems: slags: as liquid silicates,
down, 183 751