Page 49 - MODERN ELECTROCHEMISTRY

xlviii INDEX

LaPlace transformation, 382 Macroions
equation, 392 effect upon a solvent, 191
explained, 383 partial molar volumes, 192
partial differential to total differential, Mammantov, and “the cutting edge of technol-
385 ogy,” 1
schematized, 393 Marinelli and Squire, successive molecules
LaPlace transforms added to hydration shell, 150
of a constant, 584 Materials, and surfaces, 6
and dependence with concentration of time Mayer’s
and distance, 404 helpful stratagem, 317
tabulated, 384 theory, 316
and the treatment of constant flux, 398 compared with that of Debye and Hückel,
Lattice, a thermal loosening, 602 327
Lee and Tai virial coefficient approach, to ionic solu-
doubtful assumptions, 112 tions, 317
significant contribution to ionic entropies, McMillan–Mayer theory, 316
111 MD and Monte Carlo: are they just answer get-
Lee and Wheaton, their contributions to con- ters?, 322
ductance theory, 523 Mean activity coefficients, their theory, 345
Leonard–Jones equation, 45 Mean jump distance, 464
Levesqe, and autocorrelation functions, 417 a structural question, 412
Life time, Mean square distance, traveled in time t, 374
of complex ions, in molten salts, 699 Mechanistic thoughts, on dielectric breakdown,
of holes, in molten salts, 676 181
of water in hydration shells, 83 Melting points
Ligands, dependence of hydration quantities, of inorganic salts, 604
96 of tetraalkylammonium chlorides, 724
Lin, and waste disposal in molten salts, 719 Metabolism
Linearization, of the Boltzmann equation, and fuel cells, 24
237 a speculative model, 24
Linearized Poisson–Boltzmann equation, solu- Metal oxide, and silica atom, interactions, in
tion to, 239 silica networks, 734
Liquids, various properties, tabulated, 606 Methanol oxidation, and the spectra therefrom,
Liquid ammonia, the preferred nonaqueous sol- 21
vent, 543 Migration of ions
Liquid electrolytes how it happens, 441
ionic liquids, 603 independent, 440
at room temperature, 720 Mitochondrion, and a model for the energy ex-
Liquid oxide electrolytes, 726 change in biology, 25
Liquid silica, Mobilities, related to diffusion coefficients,
and fused salts, transport processes, com- 450
pared, 732 Mobility
the effect of ionic additions, 734 absolute, 445
Liquid silicates of electrons, in molten salts, 716
conductance, 730 of ions, 444
and the effect of pressure on structure, 750 from Stokes’ law, 455
and the ring anions, 743 Model, for activity coefficients, finite sized
in spectroscopy, 746 ions, 280
Lodge’s experiment, 493 Model calculations, for hydration heats, 114
Lynntech, a leading electrochemical company, Modeling approaches, to conceptual structures
32 of molten salts, 632