Page 53 - MODERN ELECTROCHEMISTRY

Iii INDEX

Relaxation time Solutions
of the drift velocity, 512 electrolytic, as seen through spectroscopy,
effect of ions upon it, 532 337
and the ionic atmosphere, 513 a part of physical chemistry?, 3
Reorientation, the key to the Conway, Bockris, and the virial coefficient approach to devia-
and Linton theory, 576 tions from ideality, 316
Residence times and hydration numbers, 165 Solution–solution boundaries, 485
Response, of a system to a stimulus, in diffu- Solution structure, and Raman effects, 84
sion, 397 Solvation
Rice–Alnut theory, in molten salt transport, 693 and the transition, 197
Richards, Nolan, and sound velocity determi- approaches, 39
nations, 61 attempts to compute it, of Kalman, 154
Ring and chain structures, in aluminum com- breadth as a field, 37
plexes, in molten salts, 712 computation approaches, 154
Ring anions entropies described, 53
formation, and liquid silicates, 744 and hydrophobic effects, 175
in liquid silicates, 742 investigative tools, 50
six-membered, in liquid silicates, 744 and molecular dynamics, 40
Room temperature molten salts, 720 and nonaqueous solutions, 74
Rossky and Friedmann, repulsive ion–ion inter- from nuclear magnetic resonance, 85
actions taken into account, 331 a quadrupole model, 107
and Raman spectra, 83
Sackur–Tetrode equation, used for ionic en- spectroscopy, use of, 40
tropy calculations, 128 and transport methods, 50
Salting in, anomalous, 174 Solvation energy, determined, the method, 52
Scattering, according to Rayleigh, 84 Solvation model, suggested by Bockris, 1949,
Self diffusion 84
coefficients, calculated, 164 Solvation numbers, 139
and molecular dynamics, 164 compressibility, 58
in molten salts, 648 coordination numbers, 140
Semiconductor–solution interface, and the dis- data, 66, 67
tribution of charge, 272 determination of vibration potentials, 58
Setchenow’s equation, plotted, 172 at high concentrations. 68
Shell of ions and electrolytes, 61
first, near an ion, 79 and mobility method, 70
spherical, near reference ion, 245 and relevant quantities, 65
Shuffling as a model for transport, in molten in salts, and vibration potentials, 64
salts, 692 Solvation of ions, on the hydrogen scale, 100
Silicates Solvation shell, a stereographic view, 178
and chain breaking, 731 Solvent
liquid and discrete polyions, 740 dynamic simulations, for aqueous solutions,
their various structures, 729 163
Slags effect, on mobility, 544
and an electrochemical theory of their com- properties, of fused nonmetallic oxides, 733
position, 753 Space charge, near an ion, 272
the importance of their composition, 752 Specific conductivity, 429
Solubility in terms of mobilities, 446
calculated, as a function of solvation, 169 tabulated, 433
ionic solvation, as a function of, 167 values of, 430
secondary solvation, changes due to, 168 Spectra, of hydration, in biological systems,
solvation, affected by 171 198