Page 55 - MODERN ELECTROCHEMISTRY

liv INDEX

van der Waal’s radius, and its distinction from Water (cont.)
other radii, 48 organized, within proteins. 38
Vectorial character, of current, 439 oriented towards ions, 47
Vibration potentials in sodium chloride, activities, 298
and the determination of solvation numbers, structure, 42
58 related to ice, 43
and their relation to the solvation numbers in research thereon, 44
salts, 63 Water molecules, 80
Virial coefficient dipolar properties, 48
approach, for solutions, 316 as dipoles, 42
and Debye and Hückel, 333 oriented towards a tetramethylammonium
Viscosities, of molten salts, 653 ion, 126
Viscosity as quadrupoles, 102
and the hole theory, 677 Water orientation, field induced, and its confir-
a kinetic theory, 756 mation with experiment, 580
of molten salts, 651 Water region, near an ion, 90
Viscous flow, as seen in hole model, 675 Water removal theory, of activity coefficients,
Viscous forces, acting on ion, 452 297
Volta, a co-discoverer of electrochemistry, 1 Webb, an early theory of the pressure near an
Volume change, where it occurs in electrostric- ion, 190
tion, 189 Wertheim, and dimer formation, calculations
Volume constant conditions, for diffusion, 690 due to Haymet, 331
von Laue, 77 White coats: a future?, 323
Wilkes, seminal contributions to molten salt
Walden’s rule, 461 chemistry, 19
Wass, and methanol oxidation, examined spec- Woodcock and Singer
troscopically, 21 their seminal calculation, 624
Wastewater treatment, Hitchens, 26 model, portrayed, 629
Water Work done
affected in structure by ions, 46 in charge moving under potential gradient, 422
and biological systems, 197 in crossing concentration gradient, 364
bound, 294 in electrostatic changes, 366
does it have a different structure in biology? in forming voids in molten salts, 637
197 in lifting weight, 365
dynamic properties, and effect on hydration Wrist watch, glucose meters?, 22
numbers, 141
free, 294 Yamashita and Fenn, technique for spraying
general properties, 534 ions into the mass spectrometer, 98
liquid, and net works, 44 Yeager, contributions to solvation heats, 119
the most common solvent, its extraordinary
properties, 41 Zaromb, Solomon, and the aluminum battery,
near a chloride ion, diagrammated, 82 19
not always the ideal solvent, 535 Zig-zag motion, of a colloid, 375