Page 51 - MODERN ELECTROCHEMISTRY

I INDEX

Ohm’s law, and ionic conductivity, 431 Planet earth, and the structure of fused oxide
Onori, and his objections to Passynski, 59 systems, 749
Onsager phenomenological equations, 494 Poisson–Boltzmann equation
Orbitals and its rigorous solution, 300
hybrid and water, 42 linearized, 238
of water, and a logical inconsistency, 301
and their effect on hydration of transition mathematics, 240
metals, diagrammated, 148 for point charged ions, 288
from hydration of transition metals, 147 schematic, 287
in water molecules, their alignment as key to Poisson’s equation
photon conduction, 577 and the charge density near the central ion,
Organic compounds, electronically conducting, 235
554 for symmetrical charge distribution, 344
Organic solutes, in liquid electrolytes at low Pollution, and oil, 31
temperatures, 722 Polyacetylene, as a photo electrode, 562
Orientation, of water molecules, near ions, Polyion model, for liquid silicates, tabulated,
91 741
Orienting dipoles and dielectric constants, Polyions
88 individual ones, 191
Osmotic coefficients, for various models, as a and liquid silicates, 740
function of ionic strength, 318 their hydration, 190
Osteryoung, seminal contributions to molten Polymer formation, in silicates, 740
salt chemistry, 19 Polymers
Oxygen transfer reactions, and the silicate, tet- electronically conducting, 554, 564
rahedra, 735 electronically conducting, diagrammated,
558
Pair correlation functions, 343 electronically conducting, various applica-
Pair–pair interactions, 321 tions, 561
Paired vacancy model, for ionic transport in Pons, and his development of FTIR, 20
molten salts, 663 Potassium–water interaction, as a function of
Palinkas, his early attempt at molecular dynam- distance, 158
ics of hydration, 154 Potential, super position of, 249
Parameter, adjustable, effect of, 284 Potential electrolytes, 226
Partial molar volumes schematic presentation, 227
defined, 56 Potential energy,
determination, and Conway’s method, 57 for proton–oxygen bonds, 572
ions in solution, 55 curves, in rotation of water molecules near
of macroions, 192 ions, 579
obtained for ions, 56 Power supplies, caught up in electron flow, 8
Passynski Pressure
criticized by Onori, 59 near an ion, due to electrostriction, 185
and his argument about compressibility, 58 near an ion, its effect on compressibility,
Phenomenological relations, and time, 504 187
Physical chemistry, related to electrochemistry, Primary hydration numbers, their values, sum-
12 marized, 145
Picture, stereoscopic, of “frozen” waters near Primary solvation sheath, and the ion-induced
sodium ion, 160 dipole itneractions, 106
Planck–Henderson Probability
equation, 500 finding oppositely charged ions near each
and integration, 501 other, 304
and the liquid junction potential, 502 function, in hole model, 634