Page 48 - MODERN ELECTROCHEMISTRY

INDEX xlvii

Ionic solutions Ions (cont.)
and computer simulation, 319 and models for entropy, 133
and dielectric constants, 92 mobility, 444
and dielectric measurements, 91 movements under electric fields, 425
and Raman spectra, 73 and partial molar volumes, 56
Ionic solution theory radii, and solvation number, 81
st
and the 21 century, 342 response to electric fields, 424
student exercises for, 349 in solution and their partial molar volume,
Ionic solvation 55
and computer simulation, 153 in solution, thermodynamic properties, 55
and entropy calculations, 130 structure near them, by spectroscopy, 72
its effect on solubility, 167 surrounded by water, 47
and models, 115 Ion size parameters, 280
surveyed, 201 tabulated, 283
Ionic solvation numbers varying with concentration?, 285
the data, 65 Ion–solvent interactions
obtained in dilute solution, five methods, and activity coefficients, 293
119 the future of research, 199
Ionic transport, the ion quadrupole model, 103
a bird’s eye view, 503 and mobilities, a simplistic theory, 70
exercises, 587 Ion–solvent relations, defined, 47
Ionic volume Ion transport, 361
function of field strength, 186 problems, 593
individual, how to obtain them, 56 Ion–water clusters, computations thereon,
Ion-induced dipole interactions, 106 157
Ion-ionic solvation, the quadrupole model, Ion–water interactions, 162
107 dependence upon quadrupole interactions,
Ion–ion interactions, 225 104
activity coefficients, 251 Irish and Davis, and effect of solvation on
chemical potential, 231 nitrate spectra, 85
strategy for understanding, 230
vibrational spectroscopy, 540 Jump frequency, a rate process, 413
theory, its parentage, 292
Ion pair formation, and noncoulombic forces, Kainthla, and the dielectric breakdown of wa-
551 ter, 183
Ion-quadrupole Kalman, her early attempts at computing static
interaction, deduced, 209 solvation, 154
model, 103 Kebarle
Ions and the pulse electron beam, 97
and the autocorrelation function, 415 his seminal work on ionic hydration in the
concentration in a variety of media, 37 gas phase, 94
detected, in liquid silicates, by spectroscopy, Kohlrausch’s law, 438
747 formulated, 458
effect on the structure of water, 46 and the independent migration of ions,
and entropy calculations, 131 439
enveloped by sheath of oriented water, 46 and ionic migration, 506
of equal radii, and their heats of solvation, in terms of ionic interactions, 519
101 Krestov
and finite size effects, 273 and the separation of ion and solvent effects
individual properties, 98 in hydration, 139
interacting with nonelectrolytes, 166 and the thermodynamics of solvation, 179