Page 44 - MODERN ELECTROCHEMISTRY

INDEX xliii

Einstein’s equation, its deduction, 449 Electroneutrality
Einstein’s relation, 448, 451 and conduction, a conflict?, 426
Einstein–Schmolukowski and drift of different ionic species, 487
theory, its mathematics, 583 its unbalance in molten electrolytes, 666
the calculation of the fraction counted, Electronically conducting polymers, 558
408 in electrochemical science, 559
equation, what fraction of the total diffusate Electronic conduction, in molten salts, 714
does it represent?, 378, 405 Electronics, medical, field of the near future,
fraction, 407 31
Electrochemical and chemical reactions, 8, 9, Electrons, flow across interfaces, 8
11, 29 Electron transfer processes, 427
Electrochemical cell, 10 Electrostatic potential, function of distance,
Electrochemical potential, its gradient, 471 from central ion, 242
Electrochemical reactor, 9, 10 Electrostatics, and work done, 366
Electrochemical windows, and low temperature Electrostriction, 185
liquid electrolytes, 722 calculated, 188
Electrochemistry and other systems, 190
and biology, 15 and volume changes, in water, 187, 189
and the center at Texas A&M University, Eley and Evans
26 statistical mechanics of ions in solution, 86
and companies, in College Station, Texas, 26 their seminal 1938 paper, 40, 114
chemical origins, 13 Enderby and Neilson, their seminal contribu-
cleaner environments, 25 tions to electrolytic solution, 78
a core science for a sustainable society, 30 Energy of activation
in the developing world, 28 cations and anions in molten salts, 680
discovered by Galvani, 1 for conductance, 658
and engineering, 15 at constant volume, 689
and electrodics, 4 in molten salt diffusion, 650
and geology, 15 for viscous flow, in liquid silicates, 737
an interdisciplinary field?, 15 Engineering, and electrochemistry, 15
definition, 1 Entropies
journals, 34 of hydration, compensation plots, 138
and metallurgy, 13 of hydration, tabulated, 113
and monograph series, 33 individual, 112
and other sciences, 12 ionic, and the evidence from reversible cells,
and progress since 1980, 18 110
related to civilization, 28 of solvation, described, 53
related to physical chemistry, 12 Entropy, librational, near ions, 132
and the theory of metabolism, 24 Entropy calculations
two kinds of, 3 and the Sackur–Tetrode equation, 128
Electrodics, 4 various models, tabulated and compared,
some characteristics, 5 134–136
Electrolytes Entropy changes, and solvation, 127
interactions, ion–ion, their relevance, 229 Entropy of hydration
potential, 226 as a function of reciprocal radius, for various
strong and weak, diagrammated, 228 models, 137
and their adiabatic compressibility, 62 possible models, 126
true and potential, 225 and relevant quantities in its calculation, 128
Electrolytic solutions, and the seminal work of Entropy of solvation,
Enderby and Nielson, 78 its dependence on radius, 54
Electron beam and Kebarle, 97 and heat of solvation, 138