Page 54 - MODERN ELECTROCHEMISTRY

INDEX Iiii

Spectroscopic methods, molten salts, 702 Thermodynamics,
Spectroscopy applied to heats of solvation, 51
detection of structural units in liquid sili- of ions in solution, 55
cates, 747 Time average positions of water near ions, 163
and structure near an ion, 72 Tools, for investigating solvation, 50
Standard partial gram ionic entropies, absolute, Transformation, chemical, involving electrons, 8
112 Transition metals
Star wars, and work on dielectric breakdown, a diagrammatic presentation of their hydra-
182 tion, 149
Step function, and diffusion there afterwards, hydration of ions, 146
403 ions, 203
Stokes, his long term collaboration with Robin- water orbitals, 147
son, 263 Transition time, in molten salts, and complex
Stokes and Robinson, and hydration numbers formation, 701
from activity measurements, 86 Translation, its entropy, for ions, 129
Stokes–Einstein relation, 454 Transport
for ionic liquids, 654 diffusion, 3
proof for molten salts, 657 experiment, in molten electrolytes, 667
tested, 655 and forces in its phenomenological treat-
Stokes’ Law, 453 ment, 367
vital to hydration number determinations, a function of concentration, 371
70 of ions, 361
Streamers, and dielectric breakdown, 180 in molten salts, various experimental ar-
Stress rangements, 670
mechanical, and moist surfaces, 6 methods, and solvation, 50
Stretching frequencies, from oxygen- and solvation numbers, 70
deuterium, 76 Transport numbers, 477
Structure breaking and the Achilles heel in the Hittorf method,
its effect upon hydration calculations, 122 492
in three dimensional lattices, 736 of cations, tabulated, 478
Structure broken region, near an ion, 123 and concentration, 479
Surfaces, their role in materials science, 6 and concentration cells, 263
Swallin’s model, small jumps, 691 determination of, 488
Swift and Sayne, and their model for primary in liquid electrolytes, how to measure them,
hydration, 86 668
System in molten salts, seven methods, 671
electrochemical, 10, 35 in molten salts, tabulated, 672
Szklarczyk in pure liquid electrolytes, 665
and the compression of ions in the double values of zero, 480
layer, 190 Transport phenomena, in liquid electrolytes, 646
and the dielectric breakdown of water, 183 Transport processes, in fused salts and liquid
silica, compared, 732
Tafel high field case, in ionic conduction, 469 Triple ions, in nonaqueous solution, 552
Temperature coefficients, of reversible cells, Triplets, 315
110 True and potential electrolytes, 225
Tetraalkylammonium chlorides, their melting True electrolytes
points, 724 and conductance, in nonaqueous solution, 553
Texas A&M University, and the development formed from crystals, 225
of electrochemistry, 26 schematic presentation, 227
Thermal loosening, of the lattice, 602 Turq, his contributions to ionic solution theory,
Thermal reaction, 11 323