Page 209 - Organic Electronics in Sensors and Biotechnology
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186    Chapter  Five


                           50
                                                        OLED
                               Double shielded, coumarin-doped Alq 3
                           40

                           30
                          I 0 /I              Shielded, Alq  OLED
                                                      3
                           20


                           10               Unshielded, Alq  OLED
                                                      3
                            0
                             0      20    40     60    80     100
                                           % Oxygen

               FIGURE 5.16 SV plots using unshielded and shielded structurally integrated
               O  sensors: OLED/PdOEP:PS/thin fi lm Si-based PD. (Reprinted with permission
                 2
               from Ref. 81, “Integrated Photoluminescence-Based Sensor Arrays: OLED
               Excitation Source/Sensor Film/Thin-Film Photodetector,” SPIE 2007.)



                   The latter higher sensitivity was achieved in part by shielding
               the electromagnetic noise generated by the pulsed current through the
               OLED and wiring when using lock-in detection.  In one approach,
                                                         81
               the shielding was achieved by placing a grounded ITO/glass, as
               shown in Fig. 5.17, over the OLED. This sensitivity is still lower than
               the sensitivity of the [Alq -based OLED]/[PdOEP:PS] module
                                        3
               obtained with a PMT, and the thin-film PD could only monitor O  in
                                                                      2
               the I mode (due to the PD’s slow speed), but it still demonstrates the
               potential ultimate success of the three-component integrated plat-
               form. As the measurement of τ is beneficial over I, the development
               of the thin-film PDs focuses currently on obtaining a detailed under-
               standing of the factors affecting their speed, in an attempt to shorten
               their response time.




                                  ITO

                             Glass

                                 OLED pixel

               FIGURE 5.17  OLED shielding confi guration (not to scale), which resulted in
               signifi cantly improved S . (Reprinted with permission from Ref. 81, “Integrated
                                 g
               Photoluminescence-Based Sensor Arrays: OLED Excitation Source/Sensor
               Film/Thin-Film Photodetector,” SPIE 2007.)
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