Page 328 - Organic Electronics in Sensors and Biotechnology
P. 328

Organic Electronics in Memories and Sensing Applications   305

                  PF-nP Dendrimers      CN-nT-CN         Diphenylanthrazoline
                  F        F          NC  S  CN
               F     F  F     F
                       F
                                             n
               F              F     Tetrachloro PTCDI-R             R
                  F        F             ClCl             N      N
                    F     F
                                   O            O       R
                    F     F
                                 R  N            N R
                    F     F
                       F           O             O
                                         ClCl
                      DB-TCV3T                        PF-6T
                                           F   F    F  F     F  F
                CN               CN
                         S                                S        S
              NC    S        S     CN     F      S                    F
                  CN            CN           S        S        S
                                                F  F    F   F    F  F
                          TB-TCV6T                          PF-nP
                                   C H  C H
                                    4 9  4 9          F   F F  F F  F
                 CN                           CN
                         S        S        S    CN
              NC     S        S       S              F                F
                  CN                           CN               n
                      C H  C H                        F   F F  F F  F
                       4 9  4 9
                                       PTCDI-PPEEB
                                   O             O
                         O                                 O
                    O        O     N             N     O        O
                                   O             O
                                       PTCDI-PPE4CN
                                     O           O
                   O       O                               O       O
              NC       O       O     N           N     O       O       CN
                                     O           O
                      DHCO-4T
                                            EHI-PITN
               O                              R               P4AQ
                 S        S        C H
           C H        S       S     6 13   O  N  O
            6 13
                                 O
                       DFHCO-4T                                   N
               O
                  S        S       C F                              n
           C F        S        S    6 13                       R
            6 13                              S  n
                                  O
          FIGURE 8.3  Structures of some other n-channel semiconductors. (Reproduced with
          permission from Ref. 4. Copyright 2004, American Chemical Society.)
               have been shown to exhibit good electron and hole mobilities. 22–23  We
               have demonstrated ambipolar CMOS-like inverters employing ambi-
                                   24
               polar pentacene OFETs.  Fullerene derivatives such as PCBM and C
                                                                        70
               have also shown ambipolar transport and circuits. 25–26  Among  the
                                                        27
               phthalocyanines, copper phthalocyanine, CuPc,  and iron phthalo-
               cyanine, FePc, and among polymers, poly(3,9-di-t-butylindeno[1,2-b]
                            28
               fluorene) (PIF),  and bis[4-dimethylaminodithiobenzyl]-nickel have
   323   324   325   326   327   328   329   330   331   332   333