Page 330 - Organic Electronics in Sensors and Biotechnology
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Organic Electronics in Memories and Sensing Applications   307


                                                              CF 3
                                                          F 2 C
                                                   CF 3
                                                              CF 2
                                                F 2 C     F 2 C
                                                   CF 2
                                                              CF 2
                                                F 2 C     F 2 C

                                                   CF 2
                                                              CF 2
                                     F 3 C      F 2 C     F 2 C

                                                              CF 2
                                                          F 2 C

                         Si             Si         Si        Si
                  H 3 CO    OCH 3  Cl       Cl Cl      Cl Cl     Cl
                                        Cl         Cl        Cl
                         OCH 3
                      PTS             FPTS       FOTS       FDTS



                                                                   OH

                                                                   P
                                                                      OH
                                                                  O
                                                ODPA

                      Me         Me
                           H                          Si  OMe
                 Me   Si   N   Si   Me        C 18 H 37
                                                       OMe
                      Me         Me
                         HMDS                       ODS
               FIGURE 8.4  Molecular structures of the commonly used SAM in organic
               electronics: PTS, phenyltrimethoxysilane; FPTS, trichloro(3,3,3-trifl uoropropyl)
               silane; FOTS, trichloro(1H,1H,2H,2H-perfl uorooctyl)silane; FDTS,
               trichloro(1H,1H,2H,2H-perfl uorodecyl)silane; ODPA, noctadecylphosphonic
               acid; HMDS, hexamethyldisilazane; ODS, octadecyltrimethoxysilane.


               combination of an anionic polyelectrolyte with a cationic surfactant,
               it has been shown that DNA, which is an anionic polyelectrolyte,
               could be quantitatively precipitated with cationic surfactant in
                     49
               water,  using hexadecyltrimethylammmonium chloride (CTMA), by
               an ion-exchange reaction 50–51  (see Fig. 8.5). The resulting DNA-lipid
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