Page 73 - Origin and Prediction of Abnormal Formation Pressures
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ORIGIN OF ABNORMAL FORMATION PRESSURES                                 55

            gypsum bed, and hydraulic conductivity of the confining layer. The gypsum-dehydration
            mechanism  in  compacting  sediments  will  produce  high  fluid  pressures  only  if  all  the
            above variables are within certain definable limits.
               This  is  also  true  for  the  montmorillonite-dehydration  model:  Hanshaw  and  Brede-
            hoeft (1968, p.  1117)  assumed that if each cubic centimeter of sediment contains  2 g of
            montmorillonite, then dehydration of montmorillonite will produce 0.33  g/cm 3 of H20.
            Enthalpy  data  from  Sudo  et  al.  (1967)  indicate  that  178  cal/cm 3 is  required  to release
            the interlayer water.  Employing the following assumed values  of  10 -6  cal cm -2  s -1  for
            a heat flow rate and  1.6  x  10 -9  cm/s  as  a burial rate,  6.3  x  101~ s would be required to
            increase the depth by  1 cm. In that time, 630 cal/cm 2 would be available from the usual
            flow  of heat  found  in  the  Earth.  There  would  be  more  than  enough  heat  available  for
            the  dehydration reaction  to proceed  (Hanshaw  and  Bredehoeft,  1968).  Interlayer water
            would be released at the rate of 5.1  x  10 -1~ cm/s. In the phase transition of gypsum, the
            reaction  went  from  a  solid to  a  solid plus  water;  however,  in  the  dehydration of mont-
            morillonite  the  dense  water  expands.  Not  all  of the  water  is  moved  from  the  reaction
            site.  If one assumes that all interlayer water has  a density of  1.4  g/cm 3 (Martin,  1962),
            expansion,  upon release  to water having  a normal  density  of  1 g/cm 3, will  result in  an
            increase  in  specific  volume  (reciprocal  of density)  of 28.5%.  Hanshaw  and  Bredehoeft
            (1968, p.  1117)  calculated that the total flow  (qo) upward or downward will be equal to
            0.285  x  0.5  x  5.1  x  10 -1~ or  7.3  x  10 -11  cm/s.  In  this  case,  a  conductivity  of  10 -12
            cm/s  and  about  106  years  would  be  required  to  approach  lithostatic  pressure  on  the
            fluid. In an actively subsiding basin such as the Gulf Coast Basin, this mechanism could
            provide  a significant increase in pore pressure if the  amount of montmorillonite is high
            and the permeability is low.



            MECHANISMS  GENERATING  ABNORMAL  FORMATION  PRESSURES
               The mechanisms responsible for generating abnormal pressures can be classified into
            three categories (see Tables 2-1  and 2-2), as indicated previously.
             (1) Changes  in  rock  pore  volume:  (a)  vertical  loading  (undercompaction);  (b)  lateral
               tectonic loading;  (c) secondary cementation.
             (2) Changes  in  the  volume  of  interstitial  fluids:  (a)  temperature  change;  (b)  mineral
               transformations;  (c)  hydrocarbon  generation;  (d)  thermogenic  decomposition  of
               hydrocarbons;  (e) migration of fluids (mainly gas).
             (3) Changes  in  fluid  pressure  (hydraulic  head)  and  movement  of  fluids:  (a)  osmosis;
               (b)  fluid  pressure  head;  (c)  oilfield  operations;  (d)  permafrost  environment;  (e)
               differences in specific weights (e.g., between gas and oil).

            Undercompaction

               Undercompaction  of  sediments  can  occur  during  rapid  sedimentation  and  burial  of
            sediments  containing  a  large  quantity  of  clay  minerals  (Rubey  and  Hubbert,  1959;
            Wilson et al.,  1977). Thus, the complete expulsion of water from the sediments does not
            occur,  and  sediments  are  left  as  a  loosely bound  system of swollen  clay particles  with
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