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Chapter 6





             Volatile Oils




             Volatile oils (similar to gas condensates) are usually found in deeper reser-
             voirs and higher temperature reservoirs. When volatile oil reservoirs are
             found in under-saturated state (initial reservoir pressure is higher than bubble
             point pressure), the fluid is essentially oil under reservoir conditions. As with
             black oils, when a volatile oil reservoir fluid is produced to surface, gas
             (which was originally dissolved in the oil) comes out of solution and
             becomes a free gas. There are several noticeable differences between black
             oils and volatile oils (McCain, 1993). Fig. 6.1 represents a typical volatile oil
             phase diagram.
                The differences between black oils and volatile oils are as follows:
               In both volatile oil and black oil fluids, the reservoir temperature is less
                than the critical temperature. However, the reservoir temperature is closer
                to the critical temperature in volatile oil reservoirs than it is in black oil
                reservoirs.
               The volatile oil reservoirs produce initially with higher producing
                gas oil ratio (GOR) than black oil reservoirs.
               The stock-tank oil is usually colored in volatile oil fluids, and darker in
                black oil fluids.
               Iso-volume lines in volatile oil fluids are shifted upward, while in black
                oil fluids they may be evenly spaced.
               Gas associated with volatile oil is gas condensate, while gas associated
                with black oil can usually be approximated with the dry gas concept (or
                the wet gas concept, when the amount of solution gas is relatively high).
                The proximity of iso-volume lines to each other, in volatile oils, implies
             that a small pressure drop in the vicinity of the well will release large
             amounts of gas around the wellbore. El-Banbi and McCain (2001), through
             detailed compositional simulation, showed that the pressure drop can result
             in large compositional and saturation changes around the wellbore. The large
             amount of gas released around the wellbore can also reduce the oil relative
             permeability and may lead to choking the well with excessive gas.







             PVT Property Correlations. DOI: https://doi.org/10.1016/B978-0-12-812572-4.00006-0
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