Page 180 - Petroleum Geology
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                                                                                   5

            Fig. 8-1. Plot of  water saturation against elevation above the oil/water contact. Note that
            there  is  no  evident  tendency  for  water  saturation  to  decrease  with elevation.  (Data of
            Thornton and Marshall, 1947, p. 73, table 1.)
            Fig.  8-2. Irreducible  water saturation measured  from cores cut using oil-base mud plotted
            against  that estimated from capillary pressure measurements. The data is plotted as least-
            squares correlation lines over approximate range of  each set of data. Except for aberrant
            top  line  (four measurements), all  correlation coefficients were statistically  significant at
            5% level  or less.  Data  from Bruce  and Welge, 1947, p. 235, table 1. The line with a circle
            is the data  of  Thornton and Marshall, 1947, p. 73, table 1. Reservoir ages range from Car-
            boniferous to Tertiary.

            the approximate range of  each set of  data. There is little doubt that the re-
            stored-state estimates are very  close to the measured  water  saturations,  and
            that estimates from capillary pressure measurements are sufficiently accurate
            and much cheaper than measurements from cores cut with an oil-base mud.
              How is this water  distributed in the pore space? It has commonly been as-
            sumed that it forms a film around the grains, confining the oil (or gas) to the
            central  parts  of  the pores.  This is what  is suggested  when we talk of  a sand-
            stone reservoir’s being  water-wet (i.e.,  preferentially  wetted  by water rather
            than oil).
              We  can make simple estimates of  how thick such a film of water would be
            about the grains.  Consider a packing  of  equal spheres. The total surface area
            of n spheres, neglecting their effective areas of  contact, is n7rd2; their volume
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