Page 211 - Petroleum Geology
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            ability to oil at the tail is probably less than it is at the head, so there may be
            a tendency for the oil stream to attenuate. Any oil left behind  as a discon-
            tinuous  phase  will  be  swept  up  by  the  next  front.  All fronts (if  there are
            more than one) will follow the paths of  local minimum potential energy on
            the upper surface of  the carrier  bed  (like an inverted river drainage system),
            so progress towards the trap will tend to bring migration paths together, and
            the accumulation will be fed by one or more streams of oil. A detailed con-
            tour map of the top of the carrrier bed would indicate the possible paths.
              Natural  carrier beds are rarely homogeneous or isotropic, so we must con-
            sider briefly  the main effects of  heterogeneity and anisotropy on migration
            paths.
              When two immiscible liquids occupy a single pore, the pressure in the wet-
            ting  liquid  is slightly less than that in the non-wetting liquid, and the non-
            wetting  liquid  occupies the position that minimizes its potential energy. The
            difference of  pressure across the liquid/liquid interface is the capillary pres-
            sure. We  are not concerned  here with isolated drops of oil in pores, but with
            a continuous network  of  oil through the pore space in a definite volume of
            the  carrier  bed.  We  are  concerned,  therefore,  with  the  macroscopic upper
            water /oil interface.
              The magnitude of  the capillary displacement pressure is a function of the
            radii  of  curvature  of  this interface within each pore along the macroscopic
            interface, such that the smaller the radius of curvature the greater the capillary
            displacement  pressure.  The radii  of  curvature  in  the  smaller  pores are less
            than  those  in  the  larger  pores, and the capillary displacement pressures re-
            quired  for  displacement  through  the  smaller  pores  are greater  than  those
            for the larger pores. The migrating oil occupies the larger pores preferentially,
            because these are the paths of least work.
               Heterogeneities  and  anisotropy  in  carrier  beds  are  generally related to
            bedding, and so affect the upward migration of oil across the bedding. Migra-
            tion across a graded carrier bed  in which the grain size, and so the pore size,
            increases upwards is facilitated by the decreasing capillary displacement pres-
            sure required and the increasing pressure available within the oil. If  the oil is
            a bubble that is large compared to a single pore, the imbalance of  capillary
            pressure at the leading and trailing surfaces impels the bubble upwards. Grading
            in  the  opposite sense retards migration.  Beds of  alternating fine and coarse
            grain that are not horizontal  lead to refraction  of the migration path up-dip
            (Hubbert,  1953, p.  1972, fig.  10). In  the coarser  beds, the flow path will
            tend to deviate updip: in the finer, more vertical.
               Similarly, the lateral migration  will also be along paths of least resistance,
            favouring the larger pores and perhaps by-passing the smaller.
               The water  in which petroleum migrates will not always be at rest, but also
            moving along an energy gradient to positions of  lower energy.
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