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270    PETROPHYSICS: RESERVOIR ROCK PROPERTIES


                   (1) Select cores that have not been dehydrated by  excessive heat or
                       cleaned excessively with solvents.
                   (2)  Remove hydrocarbons from the core by flushing it with propane and
                       then with water.
                   (3)  Measure core electrical conductivity Co vs. water conductivity Cw
                       for at least three different salinities.
                   (4)  Plot Co, against C,.
                   (5) Repeat Steps 3 and 4 until the points form a straight line as shown
                       in Figure 4.34.
                   (6) If the term CesQv/C&, evaluated at formation water salinity, is greater
                       than 0.1, the shaliness effect is significant.



                    EXAMPLE

                   Estimate the water saturation of  a sandstone formation which displays
                   the following characteristics:


                      Porosity = 25%
                      Shaly-sand formation resistivity factor, F * = 12.43
                      CEC = 0.08 meq/g
                      Formation temperature  = 230°F
                      Rw = 0.04 ohm-m
                      Rt = 4 ohm-m
                      pma = 2.65 g/cm3
                      Shaly-sand saturation exponent n* = 2


                    SOLUTION

                    Similar to Equation 4.92, the quadratic form of the Waxman and Smith
                    model in terms of resistivity is:


                    (RJ s$ + (R~R,BQ,) s, - F*R~ = o                           (4.140a)



                      The  effective  volume  concentration of  clay-exchange cation,  Qv,
                    can be estimated as follows (Equation 4.141):






                          0.08(1  - 0.25)2.65
                    Qv                      = 0.636 meq/cm3
                                (0.25)
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