Page 114 - Photonics Essentials an introduction with experiments
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Light-Emitting Diodes

          108   Photonic Devices

                        3
          space = 2 · – k . The number of k-states between k and k + dk is the
                     4
                     3
                                       2
          surface area = (d/dk)E(k) = 8 k dk. So the density of states in k-space
                     2
          is dN = 8 k dk. Starting with Eq. 6.4, we can derive the energy densi-
          ty of states:
                                     2m
                                k =     [E(k) – E g ]
                                 2
                                       2
                                                1/2
                                     2m
                                k =      [E – E g ]

                                      1/2        –1/2
                                  m
                           dk =         [E(k) – E g ]  dE             (6.5)
                                 2
                                    2
          So the density of states can be written as
                                                     1/2      1/2
                                  2m
                                                 m
                        2
                dN = 8 k dk = 8       (E – E g )·      (E – E g ) dE
                                                2

                                                   2
                                   2
                             dN    8 m 3/2  2
                                =            (E – E g ) 1/2           (6.6)
                             dE          3
                                                           1/2
          Thus, the density of states is proportional to (E – E g ) .




















                                   Photon Energy (E/E g )

          Figure 6.3. Equation 6.6 is a simple physical model of the LED electroluminescence
          spectrum. This model predicts that the peak intensity occurs at an energy slightly
          above the band gap energy, and that the shape of the luminescence spectrum is not
          symmetric about the peak energy.



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