Page 155 - Photonics Essentials an introduction with experiments
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Lasers

                                                                Lasers  149

          absorbing transitions equals the number of emitting transitions. We
          can summarize the discussion so far in a set of simple equations:

                        Emission rate = W 21 = B 21  (  ) + A 21
                          Absorption rate = W 12 = B 12  (  )
                                                                       (7.1)
                          N 1 B 12  (  ) = N 2 B 21  (  ) + N 2 A 21
          This allows us to solve for the photon density at the energy of the
          transition:

                                                     A 21

                                    N 2 A 21         B 21
                          (  ) =              =                        (7.2)
                                N 1 B 12 – N 2 B 21  N 1 B 12
                                                       – 1
                                                 N 2 B 21
          Now we will compare this expression for  (  ) to another one based
          on the Planck radiation law. We discussed Planck’s experiments in
          Chapter 1. The result of his work was to derive an expression for the
          energy density of photons. We recall that Planck discovered that the
          energy density depends on the temperature and on the color, or ener-
          gy, of an individual photon. Planck’s radiation law states

                                    16         1
                                        2
                             (  ) =                                    (7.3)
                                        3  e   /k B T  –1
            In comparing Eqs. 7.2. and 7.3, we can see some similarities. For
          example, we know from Boltzmann statistics that  N 2 /N 1 = e  E/k B T .
          Therefore, it follows that N 1 /N 2 = e  E/k B T  = e   /k B T . We can see that
          the two equations are identical when

                                      B 12 = B 21
          and
                                                 3
                                    16       8 n hf 3
                                        2
                              A 21
                                  =        =                           (7.4)
                                        3       c 3
                              B 21
          The two expressions in Eq. 7.4 are called the Einstein relations, in
          which c is the speed of light and n is the index of refraction of the
          medium involved. For semiconductors like GaAs or InP,  n is about
          3.4.
            The ratio of the spontaneous emission rate to the stimulated emis-
          sion rate is:

                                    A 21      /k B T
                              R =         = e     –1                   (7.5)
                                   ( )B 21


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